Goktas, MelahatAykac, CengizOzturk, Temel2025-05-102025-05-1020220974-36260973-710310.1007/s12039-022-02068-82-s2.0-85133697263https://doi.org/10.1007/s12039-022-02068-8https://hdl.handle.net/20.500.14720/7810In this study, we evaluated cooccurring ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP) for simultaneous one-step synthesis of the block-graft terpolymer of E-caprolactone and methyl methacrylate using polyepichlorohydrin (PECH) macroinitiator. For this purpose, the block-graft terpolymer was synthesized by ROP of a lactone and ATRP of a vinyl monomer using the PECH macroinitiator, which is an initiator suitable for both ROP and ATRP in one step. Spectral and chromatographic analyzes prove that the strategy used is successful in the simultaneous one-step preparation of the block-graft terpolymer with controlled molecular weights and narrow distributions.eninfo:eu-repo/semantics/closedAccessSimultaneous One-Step SynthesisBlock-Graft TerpolymerPolyepichlorohydrinRing-Opening PolymerizationAtom Transfer Radical PolymerizationArticle1343Q3Q3WOS:000825729800001