Zhou, JiLiu, DanXiong, YunAkinay, Yuksel2025-05-102025-05-1020200272-88421873-395610.1016/j.ceramint.2020.05.0062-s2.0-85085745715https://doi.org/10.1016/j.ceramint.2020.05.006https://hdl.handle.net/20.500.14720/7165Akinay, Yuksel/0000-0002-6171-6307In this study, the Cu-BTC and NH2-MIL 101 (Fe)@polypyrrole and polyaniline core-shell particles were prepared by in situ polymerization of pyrrole and aniline monomers on the surface of Cu-BTC and NH2-MIL 101 (Fe) for electromagnetic wave absorption applications. Firstly, the Cu-BTC (1,3,5 benzenetricarboxylic acid, BTC) and NH2-chromium (III) terephthalate (MIL-101) were synthesized by solvothermal method. Secondly, the surface of Cu-BTC and NH2-MIL 101 (Fe) mixtures were coated with polypyrrole (PPy) and polyaniline (PANI) by a polymerization of aniline (An) and pyrrole (Py) monomers and denoted as PP@Fe/Cu. For comparative studies, the aniline (An) and pyrrole (Py) monomers were polymerized in the same condition on the surface of NH2-MIL101 (Fe) powder without the presence of Cu-BTC and the final powder was denoted as PP@Fe. The morphologies, phase structures and magnetic properties of products were characterized by scanning electron microscope (SEM), X-ray diffractometer (XRD), and vibrating sample magnetometer (VSM) machines. The complex permeability and permittivity values of PP@Fe and PP@Cu/Fe were determined in the range of Ku band (12.4-18 GHz). The electromagnetic wave absorption performances were evaluated using obtained permittivity and permeability values. It was observed that PP@Fe and PP@Cu/Fe composites displayed excellent microwave absorption performances. The existence of Cu-BTC into NH2-MIL 101 (Fe) further enhanced the minimum reflection loss from - 60 dB to - 80 dB.eninfo:eu-repo/semantics/closedAccessPolyanilinePolypyrroleCu-BtcNh2-Mil 101Microwave AbsorptionArticle