Top, TubaYurderi, MehmetBulut, AhmetKarakoyun, NecdetCeylan, EsraZahmakiran, Mehmet2025-05-102025-05-1020230016-23611873-715310.1016/j.fuel.2023.1277002-s2.0-85147911312https://doi.org/10.1016/j.fuel.2023.127700https://hdl.handle.net/20.500.14720/10532Bulut, Ahmet/0000-0002-1697-8623; Yurderi, Mehmet/0000-0002-0233-8940; Karakoyun, Necdet/0000-0002-6083-6921The present work reported the development of carbon-supported bimetallic NiCo nanoparticles for H2 production in the methanolysis of AB for electricity generation from fuel cells. It was investigated by powder X-ray diffraction (P-XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) techniques. The catalytic properties of the Ni0.19Co0.81/C catalyst were carefully evaluated in terms of catalytic performance, such as different temperatures, metal [NiCo] loadings, substrate [AB] concentrations, and recyclability in 10 runs. The resulting N0.19Co0.81/C catalyst exhibits good catalytic activity with a high initial TOF of 136.65 min-1 and activation energy of 33.38 kJ mol- 1 for AB methanolysis. Moreover, in the recyclability test, the Ni0.19Co0.81/C catalyst maintained 95 % of its initial activity with 100 % conversion after ten runs.eninfo:eu-repo/semantics/closedAccessNico NanoparticlesMethanolysisAmmonia-BoraneCarbonHydrogen GenerationArticle341Q1Q1WOS:000953293500001