Caner, NurdanYurderi, MehmetBulut, AhmetKanberoglu, Gulsah SaydanKaya, MuratZahmakiran, Mehmet2025-05-102025-05-1020201144-05461369-926110.1039/d0nj01931c2-s2.0-85090391286https://doi.org/10.1039/d0nj01931chttps://hdl.handle.net/20.500.14720/7162Kaya, Murat/0000-0002-2458-8924; Bulut, Ahmet/0000-0002-1697-8623; Yurderi, Mehmet/0000-0002-0233-8940Palladium nanoparticles stabilized by an MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H(2)generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min(-1)) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.eninfo:eu-repo/semantics/closedAccessArticle4429Q2Q31243512439WOS:000553848100003