Ilter, ZulfiyeOncu, IlbeyKaragoz, M. HamdiErcan, SelamiAlhanli, Ferhat2025-05-102025-05-1020160253-51062-s2.0-84983390300https://hdl.handle.net/20.500.14720/16529Ercan, Selami/0000-0002-9528-6122This study, reports the synthesis and characterization of two new copolymers (poly[2-(pchlorophenyl)- 1,3-dioxolane-4-yl] methyl acrylate-co-styrene (PCPhDMA-co-St) and poly[2-(p-chlorophenyl)- 1,3-dioxolane- 4-yl] methyl acrylate-co-acrylonitrile (PCPhDMA-co-AN)). Copolymers were characterized by spectral (FT-IR, H-1 - NMR) and thermal analysis (TGA, DSC). Their thermodynamic properties, such as the adsorption enthalpy, Delta H-a, molar evaporation enthalpy, Delta H-v, the sorption enthalpy, Delta H-1(s), sorption free energy, Delta G(1)(s), sorption entropy, Delta S-1(s), the partial molar free energy, Delta G(1)(infinity), the partial molar heat of mixing, Delta H-1(infinity), at infinite dilution were studied by inverse gas chromatography. Depending on specific retention volumes, V-g(0), of probes the weight activity coefficients of solute probes at infinite dilution, ohm(infinity)(1), and Flory-Huggins interaction parameters,, between PCPhDMA-co-St and PCPhDMA-co-AN- solvents were investigated in the range of 413-453 K and 403-453 K, respectively.eninfo:eu-repo/semantics/closedAccessPolymerPolymer SynthesisThermodynamic PropertiesInverse Gas ChromatographySolubility ParametersArticle384Q4Q3700707WOS:000390363100013