A Facile One-Step Synthesis of Polymer Supported Rhodium Nanoparticles in Organic Medium and Their Catalytic Performance in the Dehydrogenation of Ammonia-Borane

Karahan, SenemZahmakiran, MehmetOzkar, Saim2025-05-102025-05-1020121359-73451364-548X10.1039/c1cc15864c2-s2.0-84855614573https://doi.org/10.1039/c1cc15864chttps://hdl.handle.net/20.500.14720/1304Ozkar, Saim/0000-0002-6302-1429A new type of supported rhodium nanoparticles were reproducibly prepared from N2H4BH3 reduction of [Rh(mu-Cl)(1,5-cod)](2) without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.eninfo:eu-repo/semantics/closedAccessA Facile One-Step Synthesis of Polymer Supported Rhodium Nanoparticles in Organic Medium and Their Catalytic Performance in the Dehydrogenation of Ammonia-BoraneArticle488Q2Q21180118222158916WOS:000298879000028