Kivrak, ArifErtas, Nevroz Aslan2025-05-102025-05-1020201694-7398https://search.trdizin.gov.tr/en/yayin/detay/358605/ferrocene-as-a-leaving-group-unexpected-rearrangement-reactions-for-the-synthesis-of-23-diarylnapthoquinoneshttps://hdl.handle.net/20.500.14720/9125In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids formthe new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene.eninfo:eu-repo/semantics/openAccessKimyaOrganikArticle81N/AN/A2227358605