Gulcan, MehmetZahmakiran, MehmetOzkar, Saim2025-05-102025-05-1020140926-33731873-388310.1016/j.apcatb.2013.09.0072-s2.0-84885401698https://doi.org/10.1016/j.apcatb.2013.09.007https://hdl.handle.net/20.500.14720/16424Ozkar, Saim/0000-0002-6302-1429; Gulcan, Mehmet/0000-0002-3921-8811Palladium(0) nanoparticles supported on the external surface of Cu-3(btc)(2) framework (PdNPs@Cu-3(btc)(2)) were in-situ generated from the reduction of Pd(acac)2 precursor impregnated on the Cu-3(btc)(2) support during the dehydrogenation of dimethylamine-borane in toluene at room temperature. The characterization of PdNPs@Cu-3(btc)(2) by using advanced analytical techniques shows the formation of well-dispersed palladium(0) nanoparticles supported on Cu-3(btc)(2) surface. These new palladium(0) nanoparticles were found to be the most active and the longest-lived nanocatalyst with superior reusability performance in the dehydrogenation of dimethylamine-borane at room temperature. (C) 2013 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessNanocatalystPalladium NanoparticlesMetal-Organic FrameworkDimethylamine-BoraneHydrogenArticle147N/AQ1394401WOS:000330489400044