Synthesis and Characterization of Cu(Ii), Ni(Ii), Co(Ii), Mn(Ii), and Cd(Ii) Transition Metal Complexes of Tridentate Schiff Base Derived From O-Vanillin and N-Aminopyrimidine

Gulcan, MehmetSonmez, Mehmet2025-05-102025-05-1020111042-65071563-532510.1080/10426507.2011.5535012-s2.0-80052276288https://doi.org/10.1080/10426507.2011.553501https://hdl.handle.net/20.500.14720/1737Gulcan, Mehmet/0000-0002-3921-8811Monobasic tridentate Schiff base ligand having ONS donor sequence was prepared by condensing N-aminopyrimidine-2-thione with o-vanillin. The complexes were formed by reacting ligand and the metal acetates of Cu(II), Ni(II), Co(II), Mn(II), and Cd(II) in methanol to get a series of mononuclear and dinuclear complexes. The characterization of ligand and metal complexes were carried out by elemental analyses, conductivity measurements, magnetic susceptibility data, FTIR, UV-vis, NMR, and API-ES mass spectral data. The structure of the complexes was confirmed on the basis of elemental analyses, magnetic susceptibility, API-ES mass spectral data and thermal gravitational analysis (TGA).eninfo:eu-repo/semantics/closedAccessSchiff Base Metal ComplexN-Aminopyrimidine-2-ThioneO-VanillinSynthesis and Characterization of Cu(Ii), Ni(Ii), Co(Ii), Mn(Ii), and Cd(Ii) Transition Metal Complexes of Tridentate Schiff Base Derived From O-Vanillin and N-AminopyrimidineArticle1869Q4Q419621971WOS:000299726800014