Konus, NihayetKaratas, YasarGulcan, Mehmet2025-05-102025-05-1020161553-31741553-318210.1080/15533174.2014.9888082-s2.0-84947724949https://doi.org/10.1080/15533174.2014.988808https://hdl.handle.net/20.500.14720/15340Karatas, Yasar/0000-0002-9171-7781; Gulcan, Mehmet/0000-0002-3921-8811Herein, the authors report that TiO2 supported ruthenium nanoparticles (Ru(0)/TiO2) during hydrolysis starting with RuCl3/TiO2 precatalyst act as highly active, long-lived, and reusable nanocatalyst in the hydrogen generation from the hydrolysis of ammonia-borane (NH3BH3) at room temperature. The resulting Ru(0)/TiO2 catalyze hydrogen generation from the hydrolysis of ammonia-borane with an initial turnover frequency value of 200min(-1) at 25 +/- 0.1 degrees C. More importantly, Ru(0)/TiO2 are stable enough to be isolated and bottled as solid material, which can be reused as active catalyst under the identical conditions of the first run.eninfo:eu-repo/semantics/closedAccessRutheniumNanoparticlesTitanium(Iv) OxideAmmonia-BoraneHydrogenArticle464N/AN/A534542WOS:000364854600002