Ruzgar, AdemYurderi, MehmetKaratas, YasarGulcan, MehmetZahmakiran, Mehmet2025-05-102025-05-1020240254-05841879-331210.1016/j.matchemphys.2024.1299442-s2.0-85203535368https://doi.org/10.1016/j.matchemphys.2024.129944https://hdl.handle.net/20.500.14720/11265Yurderi, Mehmet/0000-0002-0233-8940; Karatas, Yasar/0000-0002-9171-7781The demand for effective and safe chemical storage systems as an alternative energy carrier is unabated. This study reports the analysis of methylamine-borane (MeAB) as a new, efficient, and widely applicable technological storage material for mobile applications. Here, we report the preparation of tungsten (VI) oxide (WO3) supported ruthenium (Ru) nanoparticles (Ru/WO3) by impregnation-reduction method and their use as a nanocatalyst in the hydrolysis of MeAB for hydrogen (H-2) production. Ru/WO3 nanocatalyst was characterized by a combination of advanced analytical tools such as XRD, XPS, TEM, TEM-EDX, SEM, and SEM-EDX. Ru/WO3 nanocatalyst, with an average particle size of 2.16 +/- 0.23 nm obtained from TEM analysis, produces H-2 at 298 K with an initial turnover frequency (TOFinitial) value of 43.57 min(-1) in complete conversion in the hydrolysis of MeAB. In addition, the activation energy (E-a(#)), activation enthalpy (Delta H-#) and activation entropy (Delta S-#) values of the Ru/WO3 nanocatalyst were calculated as in MeAB hydrolysis are 51.54 kJ/mol, 3.7 kJ/mol and 184.57 J/mol x K, respectively, from the Arrhenius and Eyring-Polanyi equations. It was concluded that both the calculated TOFinitial value and activation parameters were quite valuable compared to previous catalysts used for MeAB hydrolysis.eninfo:eu-repo/semantics/closedAccessHeterogeneous CatalysisHydrogen GenerationMethylamine-BoraneRutheniumTungsten (Vi) OxideArticle328Q2Q1WOS:001315584900001