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Browsing by Author "Sekerci, Memet"

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    The Template Synthesis, Spectral Characterizatin and Thermal Behaviour of New Binuclear Schiff Base Complexes Derived From N-Aminopyrimidine With 2,3-Butandione
    (Walter de Gruyter Gmbh, 2006) Soenmez, Mehmet; Sekerci, Memet
    A new series of two types of acyclic binuclear Schiff base complexes, prepared by template condensation of N-aminopyrimidine and 2,3-butandione in the presence of Cu-II, Ni-II, Co-II and Zn-II in n-BuOH solution, have been characterized by IR, elemental analyses, electronic spectral data, conductivity and magnetic measurements. From conductivity measurements, it is shown that the complex of Ni-II is electrolyte. All the complexes have sub-normal magnetic moments commensurate with their binuclear nature. The thermal behaviour of the complexes has been studied by t.g. technique.
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    The Template Synthesis, Spectral Characterization and Thermal Behaviour of New Binuclear Schiff Base Complexes Derived From N-Aminopyrimidine With 2,3-Butandion
    (Serbian Chemical Soc, 2007) Sonmez, Mehmet; Sekerci, Memet
    Anew series of two types of acyclic binuclear Schiff base complexes, prepared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of Ni-II is a 1: 1 type of electrolyte. All the complexes have sub-normal magnetic moments in accordance with their binuclear nature. The thermal behaviour of the complexes was studied by thermogravimetry.