Browsing by Author "Sekerci, Memet"
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Article The Template Synthesis, Spectral Characterizatin and Thermal Behaviour of New Binuclear Schiff Base Complexes Derived From N-Aminopyrimidine With 2,3-Butandione(Walter de Gruyter Gmbh, 2006) Soenmez, Mehmet; Sekerci, MemetA new series of two types of acyclic binuclear Schiff base complexes, prepared by template condensation of N-aminopyrimidine and 2,3-butandione in the presence of Cu-II, Ni-II, Co-II and Zn-II in n-BuOH solution, have been characterized by IR, elemental analyses, electronic spectral data, conductivity and magnetic measurements. From conductivity measurements, it is shown that the complex of Ni-II is electrolyte. All the complexes have sub-normal magnetic moments commensurate with their binuclear nature. The thermal behaviour of the complexes has been studied by t.g. technique.Article The Template Synthesis, Spectral Characterization and Thermal Behaviour of New Binuclear Schiff Base Complexes Derived From N-Aminopyrimidine With 2,3-Butandion(Serbian Chemical Soc, 2007) Sonmez, Mehmet; Sekerci, MemetAnew series of two types of acyclic binuclear Schiff base complexes, prepared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of Ni-II is a 1: 1 type of electrolyte. All the complexes have sub-normal magnetic moments in accordance with their binuclear nature. The thermal behaviour of the complexes was studied by thermogravimetry.