Browsing by Author "Tunay, Zeki"

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Trace Element Analysis in Some Salvia Species by Inductively Coupled Plasma-Mass Spectrometry (icp-Ms) and Chemometric Approach
(Marmara Univ, 2020) Tunay, Zeki; Yener, Ismail; Oral, Elif Varhan; Demirkoz, Asli Barla; Tokul-Olmez, Ozge; Firat, Mehmet; Ertas, Abdulselam
In this study, the sterns, leaves, flowers, roots and mixed all parts of five Salvia species were analyzed for their trace element (Li, Be, V, Cr, Co, Ni, Cu, Zn, As, Se, Rh, Sr, Ag, Cd, Cs, Ba, Hg, TI, Pb, and U) contents using ICP-MS. The seeds, roots leaves, flowers, and mixed parts of each species were digested by concentrated nitric acid and hydrogen peroxide in a microwave by before ICP-MS the analysis. The accuracy and precision of the method were evaluated by CRM 1573a Tomato Leaves. Trace element contents in different parts of each sample were compared. Concentration of toxic elements (As, Cd, Hg and Pb) were lower than those declared by WHO, except Cr content. Cr content in the root sections of Salvia suffruticosa (SFR), S. hydrangea (SHR), S. trichoclada (STR), S. xanthocheila (SXR), leaf samples of S. kronenburgii (SKL) and S. xanthocheila (SXL). also the Cr content in the leaf sections of Salvia kronenburgii (SKL) Salvia xanthocheila (SXL) was found high. When consider the daily metal (Zn, Cu, Sr, Ba and Ni) needs It was concluded that these Salvia species can be nutritive sources. In addition, Salvia samples were classified by utilizing chemometric techniques such as Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA). While the first two main components explained 55.30% of the total variance, the first six main components explained 89.60% of total variance
Trace Elemental Analysis of Allium Species by Inductively Coupled Plasma-Mass Spectrometry (icp-Ms) With Multivariate Chemometrics
(Taylor & Francis inc, 2019) Oral, Elif Varhan; Tokul-Olmez, Ozge; Yener, Ismail; Firat, Mehmet; Tunay, Zeki; Terzioglu, Pinar; Ertas, Abdulselam
Aerial parts and roots of the 12 Allium species collected from five localities of Turkey were studied for trace elements (Ag, As, Cd, Co, Cr, Cu, Ni, Pb, Se, Tl, V, and Zn) using inductively coupled plasma mass spectrometry (ICP-MS). A tomato leaves certified reference material was used to characterize the accuracy and precision of the analysis. Each Allium species contained Se (315-2740 mu g/kg), Tl (2.75-71 mu g/kg), V (77-6790 mu g/kg), and Zn (3.73-26.6 mg/kg) which can meet the necessary daily intake of these minerals. In addition, chemometric analyses were performed using correlation analysis, principal component analysis, and hierarchical cluster analysis to determine the association of 12 trace elements in the Allium species. Using chemometrics, the distribution of elements between aerial parts and roots, and geographic collection localities of Allium species were also examined. This study is important the consumers because of the wide consumption of Allium species. This report is the first detailed characterization of the metal content of Allium species.