Ferrocene as a Leaving Group; Unexpected Rearrangement Reactions for the Synthesis of 2,3-Diarylnapthoquinones
| dc.contributor.author | Kivrak, Arif | |
| dc.contributor.author | Ertas, Nevroz Aslan | |
| dc.date.accessioned | 2025-05-10T17:17:06Z | |
| dc.date.available | 2025-05-10T17:17:06Z | |
| dc.date.issued | 2020 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | Van Yüzüncü Yil Üni̇versi̇tesi̇,Van Yüzüncü Yil Üni̇versi̇tesi̇ | en_US |
| dc.description.abstract | In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids formthe new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene. | en_US |
| dc.identifier.endpage | 27 | en_US |
| dc.identifier.issn | 1694-7398 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopusquality | N/A | |
| dc.identifier.startpage | 22 | en_US |
| dc.identifier.trdizinid | 358605 | |
| dc.identifier.uri | https://search.trdizin.gov.tr/en/yayin/detay/358605/ferrocene-as-a-leaving-group-unexpected-rearrangement-reactions-for-the-synthesis-of-23-diarylnapthoquinones | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/9125 | |
| dc.identifier.volume | 8 | en_US |
| dc.identifier.wosquality | N/A | |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Manas Journal of Engineering | en_US |
| dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Kimya | en_US |
| dc.subject | Organik | en_US |
| dc.title | Ferrocene as a Leaving Group; Unexpected Rearrangement Reactions for the Synthesis of 2,3-Diarylnapthoquinones | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |