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Electroanalytical Determination of Two Accase-Inhibing Herbicides in Soybean Products. a Theoretical Insight

dc.authorscopusid 55758299100
dc.authorscopusid 57219053455
dc.authorscopusid 59697256200
dc.authorscopusid 59520109600
dc.authorscopusid 57191446618
dc.authorscopusid 57357513400
dc.authorscopusid 57357513400
dc.contributor.author Tkach, V.V.
dc.contributor.author Morozova, T.V.
dc.contributor.author da Paiva Martins, J.I.F.
dc.contributor.author de Mascarenhas Gaivão, I.O.
dc.contributor.author Ivanushko, Y.G.
dc.contributor.author Türkmenoğlu, M.
dc.contributor.author Yagodynetś, P.I.
dc.date.accessioned 2025-06-30T15:25:52Z
dc.date.available 2025-06-30T15:25:52Z
dc.date.issued 2025
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Tkach V.V.] Chernivtsi National University, Kotsyubynsky Str. 2, Chernivtsi, 58001, Ukraine, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, s/n, Porto, 4200-065, Portugal; [Morozova T.V.] National Transport University, Omelianovych-Pavlenko Str. 1, Kyiv, 01001, Ukraine; [da Paiva Martins J.I.F.] National Transport University, Omelianovych-Pavlenko Str. 1, Kyiv, 01001, Ukraine; [de Mascarenhas Gaivão I.O.] Centro de Ciência Animal e Veterinária (CECAV), Universidade de Trás-os-Montes e Alto Douro, Quinta dos Prados, Folhadela, Vila Real, 5000-801, Portugal; [Ivanushko Y.G.] Bukovinian State Medical University, Teatralna Sq., 9, Chernivtsi, 58001, Ukraine; [Türkmenoğlu M.] Yüzüncü Yil University of Van, Bardakçı, Tuşba, Van, 65000, Turkey; [Yagodynetś P.I.] Chernivtsi National University, Kotsyubynsky Str. 2, Chernivtsi, 58001, Ukraine en_US
dc.description.abstract This study evaluates the possibility of electroanalytical detection of clethodim and fenoxaprop-p-ethyl in soybean crops and products. The electrochemical analysis may be performed at both the cathode and the anode, given the presence of donor and acceptor functional groups. Two mathematical models, each for the positive or negative polarity of the working electrode, were developed and analyzed using linear stability theory and bifurcation analysis. Either way, the electroanalytical behavior is effective and sufficient to quantify the nanomolar concentrations of both pesticides in mildly acidic and neutral medium for cathodic process and neutral to moderately alkaline in anodic. However, considering the moderately acidic environment of the soybean plant and its products, like also the electrochemical properties of both of the pesticide, the cathodic process is preferable. © 2025, Universidade Federal de Mato Grosso do Sul, Departamento de Quimica. All rights reserved. en_US
dc.identifier.doi 10.17807/orbital.v17i3.22023
dc.identifier.endpage 275 en_US
dc.identifier.issn 1984-6428
dc.identifier.issue 3 en_US
dc.identifier.scopus 2-s2.0-105008351221
dc.identifier.scopusquality Q4
dc.identifier.startpage 271 en_US
dc.identifier.uri https://doi.org/10.17807/orbital.v17i3.22023
dc.identifier.uri https://hdl.handle.net/20.500.14720/25247
dc.identifier.volume 17 en_US
dc.identifier.wosquality N/A
dc.language.iso en en_US
dc.publisher Universidade Federal de Mato Grosso do Sul, Departamento de Quimica en_US
dc.relation.ispartof Orbital en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Accase Inhibitors en_US
dc.subject Clethodim en_US
dc.subject Electrochemical Determination en_US
dc.subject Electrochemical Sensors en_US
dc.subject Fenoxaprop-P-Ethyl en_US
dc.subject Soybean en_US
dc.title Electroanalytical Determination of Two Accase-Inhibing Herbicides in Soybean Products. a Theoretical Insight en_US
dc.type Article en_US

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