Synthesis and Spectroscopic Study of Schiff Base and Some Metal Complexes of Derived From Pyrimidinethionamine With 2-Hydroxynaphthaldehyde

Abstract

2-Hidroksinaftaldehit ve 1-amino-5-benzoil-4-fenil-1H-pirimidin-2-tiyon'un toluen ortamında kondenzasyonundan oluşan Schiff bazının Cu(II), Zn(II), Ni(II) Co(II), ve Cd(II) tuzlarının reaksiyonundan sırasıyla, [Cu2(PTAHN)2].2CH3COO.H2O, [Zn(PTAHN)2].3H2O, [Ni(PTAHN)2].2H2O, [Co(PTAHN)2].3H2O, ve [Cd(PTAHN)2].4H2O kompleksleri sentezlendi. Kompleksler Elementel analiz, kondüktometri, Magnetik sussebtibilite ölçümleri, IR, NMR ve UV/VIS spektrum değerleriyle karakterize edildi.The Schiff base ligand , was derived from 2-Hydroksinaphthaldehyde with 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-thion obtained and its Cu(II), Zn(II), Ni(II) Co(II), and Cd(II) metal complexes of the typs [Cu2(PTAHN)2].2CH3COO.H2O, [Zn(PTAHN)2].3H2O, [Ni(PTAHN)2].2H2O, [Co(PTAHN)2].3H2O, and [Cd(PTAHN)2].4H2O were synthesized. The complexes have been characterized by means of elemental analyses, Conductometry, Magnetic susceptibility measurements, IR, UV/VIS and NMR spectral studies.