Pumice-Supported Ruthenium Nanoparticles as Highly Effective and Recyclable Catalyst in the Hydrolysis of Methylamine Borane
| dc.authorscopusid | 57842357800 | |
| dc.authorscopusid | 57222667564 | |
| dc.authorscopusid | 56226100100 | |
| dc.authorscopusid | 57217046714 | |
| dc.authorscopusid | 56458792800 | |
| dc.authorscopusid | 7007089321 | |
| dc.authorscopusid | 14521641300 | |
| dc.contributor.author | Dayan, O. | |
| dc.contributor.author | Kilicer, A. | |
| dc.contributor.author | Bulut, A. | |
| dc.contributor.author | Ceylan, E. | |
| dc.contributor.author | Tayfun, U. | |
| dc.contributor.author | Uzun, O. | |
| dc.contributor.author | Yurderi, M. | |
| dc.date.accessioned | 2025-05-10T16:55:22Z | |
| dc.date.available | 2025-05-10T16:55:22Z | |
| dc.date.issued | 2024 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | Dayan O., Department of Geological Engineering, Faculty of Engineering, Van Yüzüncü Yıl University, Van, 65080, Turkey; Kilicer A., Department of Geological Engineering, Faculty of Engineering, Van Yüzüncü Yıl University, Van, 65080, Turkey; Bulut A., Department of Biotechnology, Faculty of Science, Bartın University, Bartın, 74100, Turkey; Ceylan E., Forest Industry Engineering, Faculty of Forestry, Bartın University, Bartın, 74100, Turkey; Tayfun U., Basic Sciences, Faculty of Engineering, Architacture and Design, Bartın University, Bartın, 74100, Turkey; Uzun O., Rectorate of Bartın University, Bartın, 74100, Turkey; Zahmakiran M., Department of Biotechnology, Faculty of Science, Bartın University, Bartın, 74100, Turkey; Yurderi M., Electronics and Automation Department, Bartın Vocational School, Bartın University, Bartın, 74100, Turkey, Central Research Laboratory, Research & Application Center, Bartın University, Bartın, 74100, Turkey | en_US |
| dc.description.abstract | Pumice-supported Ruthenium nanoparticles were prepared by the impregnation-reduction method and investigated for hydrogen production in the methylamine borane (MeAB) hydrolysis reaction. The catalytic properties of this highly active Ru/Pumice catalyst were analyzed in terms of temperature (from 298 K to 328 K), substrate ([MeAB]) amount, metal loadings ([Ru]), and recyclability. In addition, the characterization of the obtained catalyst was investigated by inductively-coupled plasma optical emission spectroscopy (ICP-OES), powder X-ray diffraction (P-XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) imaging/spectroscopic techniques. The Ru/Pumice catalyst showed a superior initial TOF value (83.15 min−1 or 4989.30 h−1) in the MeAB hydrolysis reaction, and also the activation parameters (Ea, ΔH#, and ΔS#) from the Arrhenius and Eyring-Polonyi equations were found to be 42.4 kJ/mol, 39.8 kJ/mol, and −110.07 J/mol.K, respectively. © 2022 Hydrogen Energy Publications LLC | en_US |
| dc.identifier.doi | 10.1016/j.ijhydene.2022.07.116 | |
| dc.identifier.endpage | 10 | en_US |
| dc.identifier.issn | 0360-3199 | |
| dc.identifier.scopus | 2-s2.0-85135833121 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 1 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.ijhydene.2022.07.116 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/3475 | |
| dc.identifier.volume | 52 | en_US |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd | en_US |
| dc.relation.ispartof | International Journal of Hydrogen Energy | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Catalyst | en_US |
| dc.subject | Hydrolysis | en_US |
| dc.subject | Methylamine Borane | en_US |
| dc.subject | Pumice | en_US |
| dc.subject | Ruthenium | en_US |
| dc.title | Pumice-Supported Ruthenium Nanoparticles as Highly Effective and Recyclable Catalyst in the Hydrolysis of Methylamine Borane | en_US |
| dc.type | Article | en_US |