Synthesis and Characterization of Acyclic Metal Complexes Derived From 1,2-Dibromoethan and N-Aminopyrimidine

Abstract

1,2-Dibromoetan ile 1-amino-5-benzoil-4-fenil-1H primidin-2-on'un Fe(III),Cr(III), Co(II), Cd(II) ve Ni(II)'nin mevcudiyetinde N2O2 ve ONO asiklik ligandyapısında, [DPANi(H2O)2].2Cl.H2O, [BPACd(H2O)4].2Cl.3H2O,[BPACo2(AcO)2(H2O)2].2AcO.H2O, [DPAFe2Cl4(H2O)2]·2Cl ve[BPACrCl2(H2O)2].Cl tiplerinde asiklik kompleksleri template olarak sentezlendi.Kompleksler elementel analiz, kondüktometri, IR, TGA ve UV/VIS spektrumdeğerleriyle karakterize edildi.The template synthesis of 1,2-dibromoethan and 1-amino-5-benzoil-4-fenil-1Hprimidin-2-on in the presence of Fe(III), Cr(III), Co(II), Cd(II) and Ni(II) result inthe formation of acyclic complexes of the typs [DPANi(H2O)2].2Cl.H2O,[BPACd(H2O)4].2Cl.3H2O, [BPACo2(AcO)2(H2O)2].2AcO.H2O,[DPAFe2Cl4(H2O)2].2Cl and [BPACrCl2(H2O)2].Cl are N2O2 and ONO acyclicligands. The complexes have been characterized on the basis of elemental analyses,IR, TGA and UV/VIS spectral studies.