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One-Step Synthesis and Characterization of the Block-Graft Terpolymer Via Simultaneous Atom Transfer Radical Polymerization (Atrp) and Ring-Opening Polymerization (Rop) Techniques

dc.authorscopusid 36090008900
dc.authorscopusid 57209101030
dc.authorscopusid 55810809300
dc.contributor.author Goktas, Melahat
dc.contributor.author Aykac, Cengiz
dc.contributor.author Ozturk, Temel
dc.date.accessioned 2025-05-10T17:12:08Z
dc.date.available 2025-05-10T17:12:08Z
dc.date.issued 2022
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Goktas, Melahat; Aykac, Cengiz] Yuzuncu Yil Univ, Dept Sci Educ, TR-65100 Van, Turkey; [Ozturk, Temel] Giresun Univ, Dept Chem, TR-28200 Giresun, Turkey en_US
dc.description.abstract In this study, we evaluated cooccurring ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP) for simultaneous one-step synthesis of the block-graft terpolymer of E-caprolactone and methyl methacrylate using polyepichlorohydrin (PECH) macroinitiator. For this purpose, the block-graft terpolymer was synthesized by ROP of a lactone and ATRP of a vinyl monomer using the PECH macroinitiator, which is an initiator suitable for both ROP and ATRP in one step. Spectral and chromatographic analyzes prove that the strategy used is successful in the simultaneous one-step preparation of the block-graft terpolymer with controlled molecular weights and narrow distributions. en_US
dc.description.sponsorship Yuzunci Yil University Scientific Research Fund [FBA-2019-7880] en_US
dc.description.sponsorship This work was supported by the Yuzunci Yil University Scientific Research Fund (grant number: FBA-2019-7880). en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.doi 10.1007/s12039-022-02068-8
dc.identifier.issn 0974-3626
dc.identifier.issn 0973-7103
dc.identifier.issue 3 en_US
dc.identifier.scopus 2-s2.0-85133697263
dc.identifier.scopusquality Q3
dc.identifier.uri https://doi.org/10.1007/s12039-022-02068-8
dc.identifier.uri https://hdl.handle.net/20.500.14720/7810
dc.identifier.volume 134 en_US
dc.identifier.wos WOS:000825729800001
dc.identifier.wosquality Q3
dc.language.iso en en_US
dc.publisher indian Acad Sciences en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Simultaneous One-Step Synthesis en_US
dc.subject Block-Graft Terpolymer en_US
dc.subject Polyepichlorohydrin en_US
dc.subject Ring-Opening Polymerization en_US
dc.subject Atom Transfer Radical Polymerization en_US
dc.title One-Step Synthesis and Characterization of the Block-Graft Terpolymer Via Simultaneous Atom Transfer Radical Polymerization (Atrp) and Ring-Opening Polymerization (Rop) Techniques en_US
dc.type Article en_US

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