Synthesis of Novel Artemisinin Derivatives and Their Electrochemical Properties
| dc.authorid | Kavak, Emrah/0000-0002-6161-2030 | |
| dc.authorid | Ulas, Berdan/0000-0003-0650-0316 | |
| dc.authorid | Kivrak, Arif/0000-0003-4770-2686 | |
| dc.authorid | Kivrak, Hilal/0000-0001-8001-7854 | |
| dc.authorscopusid | 57696449300 | |
| dc.authorscopusid | 56891345500 | |
| dc.authorscopusid | 57216928471 | |
| dc.authorscopusid | 57203167255 | |
| dc.authorscopusid | 25959155500 | |
| dc.authorscopusid | 8694518300 | |
| dc.authorwosid | Özok Arıcı, Ömrüye/Glu-5294-2022 | |
| dc.authorwosid | Kivrak, Hilal/Hji-7095-2023 | |
| dc.authorwosid | Kivrak, Arif/Aaq-8432-2021 | |
| dc.authorwosid | Ulaş, Berdan/Aai-9979-2021 | |
| dc.authorwosid | Kavak, Emrah/Gls-1399-2022 | |
| dc.authorwosid | Kivrak, Arif/W-2196-2017 | |
| dc.authorwosid | Kivrak, Hilal/Aaq-8663-2021 | |
| dc.contributor.author | Esen, Meryem | |
| dc.contributor.author | Kavak, Emrah | |
| dc.contributor.author | Ozok-Arici, Omruye | |
| dc.contributor.author | Ulas, Berdan | |
| dc.contributor.author | Kivrak, Hilal | |
| dc.contributor.author | Kivrak, Arif | |
| dc.date.accessioned | 2025-05-10T17:36:27Z | |
| dc.date.available | 2025-05-10T17:36:27Z | |
| dc.date.issued | 2022 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Esen, Meryem; Kavak, Emrah] Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey; [Ozok-Arici, Omruye; Kivrak, Hilal] Eskisehir Osmangazi Univ, Fac Engn & Architectural Sci, Dept Chem Engn, TR-26040 Eskisehir, Turkey; [Ulas, Berdan] Yuzuncu Yil Univ, Fac Engn, Dept Chem Engn, TR-65000 Van, Turkey; [Kivrak, Hilal] Eskisehir Osmangazi Univ, Translat Med Res & Clin Ctr, TR-26040 Eskisehir, Turkey; [Kivrak, Arif] Eskisehir Osmangazi Univ, Fac Sci & Arts, Dept Chem, TR-26040 Eskisehir, Turkey | en_US |
| dc.description | Kavak, Emrah/0000-0002-6161-2030; Ulas, Berdan/0000-0003-0650-0316; Kivrak, Arif/0000-0003-4770-2686; Kivrak, Hilal/0000-0001-8001-7854 | en_US |
| dc.description.abstract | In present, new artemisinin-based organic compounds (1-6) are designed and synthesized in excellent yields (up to 97 %) via Steglich Esterification reactions. All new artemisinin derivatives are tested as anode catalysts for hydrazine electrooxidation reactions with electrochemical methods in 1 M KOH/0.5 M N2H4 solution. Hybrid molecule 1 exhibits the best catalytic activity in hydrazine electrooxidation reaction with 2.28 mA cm(-2) value. Moreover, response surface methodology (RSM) is applied to investigate of optimum electrode conditions. By using optimum conditions, hydrazine electrooxidation is obtained as 3.55324 mA cm(-2). As a result, artemisinin-based hybrid compounds may be alternative, and next-generation anode catalyst for direct hydrazine fuel cells. | en_US |
| dc.description.sponsorship | Eskisehir Osmangazi University BAP [FOA-2021-2203]; COST Action [CA17104] | en_US |
| dc.description.sponsorship | The authors thank to Eskisehir Osmangazi University BAP (Project No: FOA-2021-2203) for chemicals and solvents. The author (A. Kivrak) would like to acknowledge networking contribution by the COST Action CA17104 "New diagnostic and therapeutic tools against multidrug resistant tumours". | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1002/slct.202201223 | |
| dc.identifier.issn | 2365-6549 | |
| dc.identifier.issue | 19 | en_US |
| dc.identifier.scopus | 2-s2.0-85130254258 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.uri | https://doi.org/10.1002/slct.202201223 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/14094 | |
| dc.identifier.volume | 7 | en_US |
| dc.identifier.wos | WOS:000797175200001 | |
| dc.identifier.wosquality | Q3 | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley-v C H verlag Gmbh | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Anode Catalyst | en_US |
| dc.subject | Artemisinin | en_US |
| dc.subject | Electrooxidation | en_US |
| dc.subject | Energy | en_US |
| dc.subject | Heterocycles | en_US |
| dc.subject | Rsm | en_US |
| dc.subject | Organocatalysis | en_US |
| dc.title | Synthesis of Novel Artemisinin Derivatives and Their Electrochemical Properties | en_US |
| dc.type | Article | en_US |