Preparation and Detailed Characterization of Zirconia Nanopowder Supported Rhodium (0) Nanoparticles for Hydrogen Production From the Methanolysis of Methylamine-Borane in Room Conditions
| dc.authorid | Karatas, Yasar/0000-0002-9171-7781 | |
| dc.authorid | Gulcan, Mehmet/0000-0002-3921-8811 | |
| dc.authorscopusid | 57204638059 | |
| dc.authorscopusid | 57081059100 | |
| dc.authorscopusid | 8226754300 | |
| dc.authorscopusid | 24558887900 | |
| dc.authorwosid | Gülcan, Mehmet/Aat-1504-2021 | |
| dc.authorwosid | Karatas, Yasar/Aam-7945-2020 | |
| dc.contributor.author | Kanat, Mehmet | |
| dc.contributor.author | Karatas, Yasar | |
| dc.contributor.author | Gulcan, Mehmet | |
| dc.contributor.author | Anil, Baris | |
| dc.date.accessioned | 2025-05-10T17:43:59Z | |
| dc.date.available | 2025-05-10T17:43:59Z | |
| dc.date.issued | 2018 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Kanat, Mehmet; Karatas, Yasar; Gulcan, Mehmet] Van Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey; [Anil, Baris] Ataturk Univ, Fac Sci, Dept Chem, TR-25030 Erzurum, Turkey | en_US |
| dc.description | Karatas, Yasar/0000-0002-9171-7781; Gulcan, Mehmet/0000-0002-3921-8811 | en_US |
| dc.description.abstract | Uniformly dispersed Rh (0) nanoparticles supported on zirconia nanopowder were synthesized by a two-step and simple ex-situ method summarized by mixing rhodium (III) chloride hydrate with zirconia (nano-ZrO2) aqueous solution in ambient conditions followed by reduction with NaBH4. The ex-situ prepared nano-ZrO2 supported Rh (0) nano-particles (Rh/nano-ZrO2) were characterized by various spectroscopic methods, including TEM, TEM-EDX, HR-TEM, P-XRD, XPS and ICP-OES. The catalytic activity of Rh (0) nano-particles is 1050 h(-1) in terms of initial turnover frequency (TOF), which is the first study in the literature to produce hydrogen by catalytic methanolysis of methylamine-borane. In addition, the catalytic methanolysis of methylamine-borane by using Rh (0) nanoparticles was carried out in different catalyst/substrate concentrations and different temperatures to reveal rate equation and kinetic parameters. Consequently, Rh (0) nanoparticles are taken into account as an encouraging catalyst for the methanolysis of methylamine-borane and for providing a more fertile hydrogen storage gain in fuel cell operations. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. | en_US |
| dc.description.sponsorship | Van YuzuncuYil University [FYL-2018-6863] | en_US |
| dc.description.sponsorship | This study was financed by Research Found of Van YuzuncuYil University (Project ID: FYL-2018-6863). | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1016/j.ijhydene.2018.10.130 | |
| dc.identifier.endpage | 22556 | en_US |
| dc.identifier.issn | 0360-3199 | |
| dc.identifier.issn | 1879-3487 | |
| dc.identifier.issue | 50 | en_US |
| dc.identifier.scopus | 2-s2.0-85056542286 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 22548 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.ijhydene.2018.10.130 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/16022 | |
| dc.identifier.volume | 43 | en_US |
| dc.identifier.wos | WOS:000452817200004 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Pergamon-elsevier Science Ltd | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Rhodium | en_US |
| dc.subject | Hydrogen | en_US |
| dc.subject | Zirconia Nanopowder | en_US |
| dc.subject | Methylamine-Borane | en_US |
| dc.subject | Methanolysis | en_US |
| dc.title | Preparation and Detailed Characterization of Zirconia Nanopowder Supported Rhodium (0) Nanoparticles for Hydrogen Production From the Methanolysis of Methylamine-Borane in Room Conditions | en_US |
| dc.type | Article | en_US |