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Liquefaction of Giant Fennel (Ferula Orientalis L.) in Supercritical Organic Solvents: Effects of Liquefaction Parameters on Product Yields and Character

dc.authorscopusid 54879310600
dc.authorscopusid 36729659300
dc.contributor.author Aysu, Tevfik
dc.contributor.author Kucuk, Mehmet Masuk
dc.date.accessioned 2025-05-10T17:22:31Z
dc.date.available 2025-05-10T17:22:31Z
dc.date.issued 2013
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Aysu, Tevfik; Kucuk, Mehmet Masuk] Yuzuncu Yil Univ, Fac Educ, TR-65080 Van, Turkey en_US
dc.description.abstract Ferule orientalis L stalks were liquefied in an autoclave in supercritical organic solvents (methanol, ethanol, 2-propanol, acetone and 2-butanol) with (NaOH, Na2CO3, ZnCl2) and without catalyst at five different temperatures ranging from 240 degrees C to 320 degrees C. The amounts of solid (unconverted raw material), liquid (bio-oil) and gas produced, as well as the composition of the resulting liquid phase, were determined. The effects of various parameters such as temperature, solvent, catalyst and ratio of catalyst on product yields were investigated. The results showed that conversion highly depends on the temperature and catalyst. The highest bio-oil yield (53.97%) was obtained using acetone with 10% zinc chloride at 300 degrees C. The liquid products were extracted with benzene and diethyl ether. Some of selected liquid products (bio-oils) were analyzed by elemental, FT-IR and GC-MS. 126 different compounds were identified by GC-MS in the liquid products obtained in ethanol at 300 degrees C. (C) 2013 Elsevier B.V. All rights reserved. en_US
dc.description.sponsorship Yuzuncu Yil University Research Fund; [2013-FBE-D004] en_US
dc.description.sponsorship This study was supported by Yuzuncu Yil University Research Fund, and we gratefully acknowledge the financial support of this study (no: 2013-FBE-D004). en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.doi 10.1016/j.supflu.2013.09.001
dc.identifier.endpage 123 en_US
dc.identifier.issn 0896-8446
dc.identifier.issn 1872-8162
dc.identifier.scopus 2-s2.0-84884828799
dc.identifier.scopusquality Q1
dc.identifier.startpage 104 en_US
dc.identifier.uri https://doi.org/10.1016/j.supflu.2013.09.001
dc.identifier.uri https://hdl.handle.net/20.500.14720/10608
dc.identifier.volume 83 en_US
dc.identifier.wos WOS:000327171600014
dc.identifier.wosquality Q2
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Biomass en_US
dc.subject Bio-Oil en_US
dc.subject Thermochemical Process en_US
dc.subject Supercritical Liquefaction en_US
dc.subject Organic Solvent en_US
dc.subject Ferula Orientalis L. en_US
dc.title Liquefaction of Giant Fennel (Ferula Orientalis L.) in Supercritical Organic Solvents: Effects of Liquefaction Parameters on Product Yields and Character en_US
dc.type Article en_US

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