Synthesized Polyvidone-Stabilized Rh(0) Nanoparticles Catalyzed the Hydrolytic Dehydrogenation of Methylamine-Borane in Ambient Conditions
| dc.authorid | Gulcan, Mehmet/0000-0002-3921-8811 | |
| dc.authorid | Karatas, Yasar/0000-0002-9171-7781 | |
| dc.authorscopusid | 8226754300 | |
| dc.authorscopusid | 57081059100 | |
| dc.authorwosid | Karatas, Yasar/Aam-7945-2020 | |
| dc.authorwosid | Gülcan, Mehmet/Aat-1504-2021 | |
| dc.contributor.author | Gulcan, M. | |
| dc.contributor.author | Karatas, Y. | |
| dc.date.accessioned | 2025-05-10T17:03:33Z | |
| dc.date.available | 2025-05-10T17:03:33Z | |
| dc.date.issued | 2017 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Gulcan, M.; Karatas, Y.] Yuzuncu Yil Univ, Sci Fac, Inorgan Chem Dept, Van, Turkey | en_US |
| dc.description | Gulcan, Mehmet/0000-0002-3921-8811; Karatas, Yasar/0000-0002-9171-7781 | en_US |
| dc.description.abstract | Polyvidone (PVP40)-stabilized Rh nanoparticles (Rh@PVP40) were synthesized via a classical alcohol reduction technique and were characterized by carrying out TEM, HR-TEM, TEM/EDX, P-XRD analysis, UV/Vis and XPS spectroscopy investigations. Approximately, non-touch each other 100 particles in were counted TEM image in 50 nm scale and the average particle size of Rh@PVP40 nanocatalyst was found to be 3.32 +/- 0.26 nm. The prepared nanoparticles were found to be one of the most efficient catalytic systems in the literature, with a high TOF value (185.91 min(-1)) and low activation energy (43.88 kJ mol(-1)) for the hydrolytic dehydrogenation of a methylamine-borane compound. Analysis of the effects of catalyst and substrate concentrations on the catalytic reaction indicated that the reaction proceeded to the 1.37-order of the catalyst concentration and nearly zero order of the substrate concentration. | en_US |
| dc.description.sponsorship | Van Yuzuncu Yil University | en_US |
| dc.description.sponsorship | Authors thank the Research Fund of Van Yuzuncu Yil University for financial support. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1039/c7nj02481a | |
| dc.identifier.endpage | 11845 | en_US |
| dc.identifier.issn | 1144-0546 | |
| dc.identifier.issn | 1369-9261 | |
| dc.identifier.issue | 20 | en_US |
| dc.identifier.scopus | 2-s2.0-85031048234 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 11839 | en_US |
| dc.identifier.uri | https://doi.org/10.1039/c7nj02481a | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/5744 | |
| dc.identifier.volume | 41 | en_US |
| dc.identifier.wos | WOS:000412639800042 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Soc Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Synthesized Polyvidone-Stabilized Rh(0) Nanoparticles Catalyzed the Hydrolytic Dehydrogenation of Methylamine-Borane in Ambient Conditions | en_US |
| dc.type | Article | en_US |