Facile and Rapid Synthesis of Microwave Assisted Pd Nanoparticles as Non-Enzymatic Hydrogen Peroxide Sensor
dc.authorid | Kivrak, Hilal/0000-0001-8001-7854 | |
dc.authorid | Kivrak, Arif/0000-0003-4770-2686 | |
dc.authorscopusid | 58324442300 | |
dc.authorscopusid | 25959155500 | |
dc.authorscopusid | 8694518300 | |
dc.authorscopusid | 57189211902 | |
dc.authorscopusid | 56728563800 | |
dc.authorscopusid | 56728709700 | |
dc.authorwosid | Kivrak, Arif/Aaq-8432-2021 | |
dc.authorwosid | Kivrak, Hilal/Hji-7095-2023 | |
dc.authorwosid | Kivrak, Hilal/Aaq-8663-2021 | |
dc.authorwosid | Kivrak, Arif/W-2196-2017 | |
dc.contributor.author | Sahin, Ozlem | |
dc.contributor.author | Kivrak, Hilal | |
dc.contributor.author | Kivrak, Arif | |
dc.contributor.author | Kazici, Hilal Celik | |
dc.contributor.author | Alal, Orhan | |
dc.contributor.author | Atbas, Dilan | |
dc.date.accessioned | 2025-05-10T17:28:40Z | |
dc.date.available | 2025-05-10T17:28:40Z | |
dc.date.issued | 2017 | |
dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
dc.department-temp | [Sahin, Ozlem] Selcuk Univ, Dept Chem Engn, Konya 42031, Turkey; [Kivrak, Hilal; Kazici, Hilal Celik; Alal, Orhan; Atbas, Dilan] Yuzuncu Yil Univ, Dept Chem Engn, Van 65081, Turkey; [Kivrak, Arif] Yuzuncu Yil Univ, Dept Chem, Van 65081, Turkey | en_US |
dc.description | Kivrak, Hilal/0000-0001-8001-7854; Kivrak, Arif/0000-0003-4770-2686 | en_US |
dc.description.abstract | Carbon supported Pd catalyst was prepared with microwave-assisted polyol method (M-Pd@C) and investigated sensing activity for non-enzymatic hydrogen peroxide (H2O2). Moreover, M-Pd@C and Pd@C catalyst which synthesized via polyol method (P-Pd@C) were compared to each other in terms of electrocatalytic activity. X-ray diffraction (XRD), X-ray photo electron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to investigate structural and morphological properties of these catalysts. Furthermore, electrochemical measurements were performed via cyclic voltammetry (CV), chronoamperometry (CA) techniques. CV results exhibited that M-Pd/C catalyst showed perfect electrocatalytic activity in terms of reduction of H2O2. M-Pd/C catalyst showed a fast response of less than 7 s with a linear range of 5.0x10(-3)-11.0 mM and a relatively low detection limit of 1.2 mu M amperometric response. M-Pd/C catalyst exhibited great selectivity for detecting H2O2 in the existence of several hindering species such as uric acid and ascorbic acid. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK) project [113Z249, 114M156, 114Z042] | en_US |
dc.description.sponsorship | CHI 660E potentiostat employed in electrochemical measurements was purchased from The Scientific and Technological Research Council of Turkey (TUBITAK) project (project no: 113Z249). The chemicals were purchased from TUBITAK project (Project no: 114M156). Anton Paar monowave reactor was purchased from TUBITAK project (project no: 114Z042). XRD measurements were performed at Selcuk University central laboratory. XPS and TEM measurements were conducted at METU central laboratory. | en_US |
dc.description.woscitationindex | Science Citation Index Expanded | |
dc.identifier.doi | 10.20964/2017.01.26 | |
dc.identifier.endpage | 769 | en_US |
dc.identifier.issn | 1452-3981 | |
dc.identifier.issue | 1 | en_US |
dc.identifier.scopus | 2-s2.0-85009923601 | |
dc.identifier.scopusquality | Q3 | |
dc.identifier.startpage | 762 | en_US |
dc.identifier.uri | https://doi.org/10.20964/2017.01.26 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14720/12109 | |
dc.identifier.volume | 12 | en_US |
dc.identifier.wos | WOS:000396470000064 | |
dc.identifier.wosquality | Q4 | |
dc.language.iso | en | en_US |
dc.publisher | Esg | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Pd Nanoparticles | en_US |
dc.subject | Microwave Assisted Polyol Method | en_US |
dc.subject | Non-Enzymatic | en_US |
dc.subject | Hydrogen Peroxide Sensor | en_US |
dc.title | Facile and Rapid Synthesis of Microwave Assisted Pd Nanoparticles as Non-Enzymatic Hydrogen Peroxide Sensor | en_US |
dc.type | Article | en_US |