One-Step Synthesis and Characterization of Poly(ε-Caprolactone) Thermo-Responsive Block Copolymers Via Raft and Rop Techniques
| dc.authorscopusid | 36090008900 | |
| dc.authorscopusid | 57210927903 | |
| dc.contributor.author | Goktas, Melahat | |
| dc.contributor.author | Olgun, Berivan | |
| dc.date.accessioned | 2025-05-10T17:25:47Z | |
| dc.date.available | 2025-05-10T17:25:47Z | |
| dc.date.issued | 2019 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Goktas, Melahat; Olgun, Berivan] Yuzuncu Yil Univ, Dept Sci Educ, TR-65100 Van, Turkey | en_US |
| dc.description.abstract | In this study, well-defined thermo-responsive block copolymers of poly(epsilon-caprolactone)-b-poly(N-isopropylacrylamide) with narrow molecular weight distribution were synthesized in one-step via reversible addition-fragmentation chain transfer (RAFT) polymerization and ring-opening polymerization (ROP) methods using dual RAFT-ROP initiator which was obtained via the reaction of 3-chloro-1,2-propanediol with the potassium salt of ethyl xanthogenate. Thermo-responsive block copolymers were obtained in high yield and high molecular weight. The characterization of the products was accomplished by NMR and FTIR spectroscopy, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimetry. Furthermore, thermo-responsive properties of the copolymers were verified by UV, and fractional precipitation techniques. | en_US |
| dc.description.sponsorship | Yuzunci Yil University Scientific Research Fund [FBA-2016-5036] | en_US |
| dc.description.sponsorship | This work was supported by the Yuzunci Yil University Scientific Research Fund (grand number: FBA-2016-5036). | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1134/S1560090419040055 | |
| dc.identifier.endpage | 429 | en_US |
| dc.identifier.issn | 1560-0904 | |
| dc.identifier.issn | 1555-6123 | |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopus | 2-s2.0-85071942838 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 421 | en_US |
| dc.identifier.uri | https://doi.org/10.1134/S1560090419040055 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/11481 | |
| dc.identifier.volume | 61 | en_US |
| dc.identifier.wos | WOS:000483800600004 | |
| dc.identifier.wosquality | Q4 | |
| dc.language.iso | en | en_US |
| dc.publisher | Maik Nauka/interperiodica/springer | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | One-Step Synthesis and Characterization of Poly(ε-Caprolactone) Thermo-Responsive Block Copolymers Via Raft and Rop Techniques | en_US |
| dc.type | Article | en_US |