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Efficient Transfer Hydrogenation Reactions With Quinazoline-Based Ruthenium Complexes

dc.authorid Karabuga, Semistan/0000-0001-9753-206X
dc.authorid Karakaya, Idris/0000-0001-6143-8864
dc.authorid Karakaya, Idris/0000-0002-3590-7206
dc.authorid Gumus, Selcuk/0000-0002-8628-8943
dc.authorscopusid 8630507300
dc.authorscopusid 56449113800
dc.authorscopusid 56037079600
dc.authorscopusid 6602962437
dc.authorwosid Karakaya, Idris/Itt-7988-2023
dc.authorwosid Karabuga, Semistan/Aai-8953-2021
dc.authorwosid Karabuga, Semistan/A-3136-2016
dc.contributor.author Karabuga, Semistan
dc.contributor.author Bars, Songul
dc.contributor.author Karakaya, Idris
dc.contributor.author Gumus, Selcuk
dc.date.accessioned 2025-05-10T17:42:12Z
dc.date.available 2025-05-10T17:42:12Z
dc.date.issued 2015
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Karabuga, Semistan; Bars, Songul] Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey; [Karakaya, Idris] Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey; [Gumus, Selcuk] Yuzuncu Yil Univ, Dept Chem, Fac Sci, TR-65080 Van, Turkey en_US
dc.description Karabuga, Semistan/0000-0001-9753-206X; Karakaya, Idris/0000-0001-6143-8864; Karakaya, Idris/0000-0002-3590-7206; Gumus, Selcuk/0000-0002-8628-8943 en_US
dc.description.abstract (4-Phenylquinazolin-2-yl)methanamine was synthesized in high yield by starting from naturally and commercially available glycine in a few steps. The ligand was reacted with RuCl2(PPh3)(3) and RuCl2(PPh3) dppb to obtain N-heterocyclic ruthenium(II) complexes. We have examined these catalysts in transfer hydrogenation of acetophenone derivatives and excellent conversions of up to 99% and high TOF values of up to 118,800 h(-1) using 0.1 mol % of catalyst were achieved. (C) 2014 Elsevier Ltd. All rights reserved. en_US
dc.description.sponsorship Scientific and Technological Research Council, Turkey (TUBITAK) [KBAG-112T816] en_US
dc.description.sponsorship Financial support from the Scientific and Technological Research Council, Turkey (TUBITAK) (KBAG-112T816) is gratefully acknowledged. en_US
dc.description.woscitationindex Science Citation Index Expanded - Index Chemicus - Current Chemical Reactions
dc.identifier.doi 10.1016/j.tetlet.2014.11.027
dc.identifier.endpage 104 en_US
dc.identifier.issn 0040-4039
dc.identifier.issn 1873-3581
dc.identifier.issue 1 en_US
dc.identifier.scopus 2-s2.0-84918582537
dc.identifier.scopusquality Q3
dc.identifier.startpage 101 en_US
dc.identifier.uri https://doi.org/10.1016/j.tetlet.2014.11.027
dc.identifier.uri https://hdl.handle.net/20.500.14720/15498
dc.identifier.volume 56 en_US
dc.identifier.wos WOS:000348259800016
dc.identifier.wosquality Q3
dc.language.iso en en_US
dc.publisher Pergamon-elsevier Science Ltd en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Ruthenium en_US
dc.subject Quinazoline en_US
dc.subject Transfer Hydrogenation en_US
dc.subject Ketone en_US
dc.subject Secondary Alcohols en_US
dc.title Efficient Transfer Hydrogenation Reactions With Quinazoline-Based Ruthenium Complexes en_US
dc.type Article en_US

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