Cettaertalyst-Free Hydrogenation of Alkenes and Alkynes With Hydrazine in the Presence of Oxygen
| dc.authorid | Menges, Nurettin/0000-0002-5990-6275 | |
| dc.authorscopusid | 23973608700 | |
| dc.authorscopusid | 7006382595 | |
| dc.authorwosid | Menges, Nurettin/F-9678-2016 | |
| dc.contributor.author | Menges, Nurettin | |
| dc.contributor.author | Balci, Metin | |
| dc.date.accessioned | 2025-05-10T17:45:46Z | |
| dc.date.available | 2025-05-10T17:45:46Z | |
| dc.date.issued | 2014 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Menges, Nurettin; Balci, Metin] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey; [Menges, Nurettin] Yuzuncu Yil Univ, Fac Pharm, TR-65080 Van, Turkey | en_US |
| dc.description | Menges, Nurettin/0000-0002-5990-6275 | en_US |
| dc.description.abstract | A series of alkenes and alkynes was subjected to reduction with hydrazine hydrate in ethanol in the presence of oxygen. An efficient method was developed for the reduction of C-C double bonds and C-C triple bonds with diimide, generated in situ from hydrazine hydrate by oxidation with oxygen. The reduction process proceeded for 24-48 hours with high chemoselectivity and excellent yields. This reduction procedure offers synthetic advantages over metal-catalyzed hydrogenation as well as other systems. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-112 T360]; Middle East Technical University; Turkish Academy of Sciences (TUBA); BIDEB-TUBITAK | en_US |
| dc.description.sponsorship | We are indebted to the Scientific and Technological Research Council of Turkey (TUBITAK, Grant No. TBAG-112 T360), the Middle East Technical University, and the Turkish Academy of Sciences (TUBA) for financial support of this work. N.M. is grateful for a scholarship provided by BIDEB-TUBITAK. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded - Index Chemicus - Current Chemical Reactions | |
| dc.identifier.doi | 10.1055/s-0033-1340554 | |
| dc.identifier.endpage | 676 | en_US |
| dc.identifier.issn | 0936-5214 | |
| dc.identifier.issn | 1437-2096 | |
| dc.identifier.issue | 5 | en_US |
| dc.identifier.scopus | 2-s2.0-84895930791 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 671 | en_US |
| dc.identifier.uri | https://doi.org/10.1055/s-0033-1340554 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/16453 | |
| dc.identifier.volume | 25 | en_US |
| dc.identifier.wos | WOS:000332212500011 | |
| dc.identifier.wosquality | Q3 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme verlag Kg | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Reduction | en_US |
| dc.subject | Oxidation | en_US |
| dc.subject | Hydrazine | en_US |
| dc.subject | Hydrogenation | en_US |
| dc.subject | Diimide | en_US |
| dc.title | Cettaertalyst-Free Hydrogenation of Alkenes and Alkynes With Hydrazine in the Presence of Oxygen | en_US |
| dc.type | Article | en_US |