Expanding the Realm of Soluble Narrow Band Gap Polymers With a Benzobisthiadiazole Derivative
| dc.authorscopusid | 56891740900 | |
| dc.authorscopusid | 54782763000 | |
| dc.authorwosid | Özkut, Merve/Aad-7011-2019 | |
| dc.contributor.author | Us, Cansu N. | |
| dc.contributor.author | Ozkut, Merve Icli | |
| dc.date.accessioned | 2025-05-10T17:40:53Z | |
| dc.date.available | 2025-05-10T17:40:53Z | |
| dc.date.issued | 2016 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Us, Cansu N.; Ozkut, Merve Icli] Yuzuncu Yil Univ, Dept Chem Engn, Fac Engn & Architecture, TR-65080 Van, Turkey | en_US |
| dc.description.abstract | A donor acceptor donor based soluble and narrow band gap pi-conjugated electrochromic polymer, poly(4,8-bis(3,3-dihexyl-3,4-dihydro-2H-thieno [3,4-b] [1,4] dioxepin-5-yl)b enzo [1,2c;4,5-c']bis[1,2,5]thiadiazole) (P1), was electrochemically (P1-E) and chemically (P1-C) synthesized. Cyclic voltammetry and UV-vis-NIR absorption measurements showed that P1 has a low band gap ranging from 0.59 to 1.1 eV, depending on the band gap determination and synthesis (chemical or electrochemical) methods. P1 demonstrated an ambipolar electrochemical behavior. The color of the polymer was gray in its neutral state and switched to green (first oxidation state) and blue (second oxidation state) upon oxidation and to brown upon reduction. | en_US |
| dc.description.sponsorship | Scientific and Technical Research Council of Turkey [TUBITAK-214Z306] | en_US |
| dc.description.sponsorship | We wish to express our thanks to the Scientific and Technical Research Council of Turkey (TUBITAK-214Z306) for their financial support. Also, we gratefully thank Prof. Dr. Atilla Cihaner and Dr. Canan Karabay for GPC analysis of the polymers. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1021/acs.macromol.6b00302 | |
| dc.identifier.endpage | 3015 | en_US |
| dc.identifier.issn | 0024-9297 | |
| dc.identifier.issn | 1520-5835 | |
| dc.identifier.issue | 8 | en_US |
| dc.identifier.scopus | 2-s2.0-84967019341 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 3009 | en_US |
| dc.identifier.uri | https://doi.org/10.1021/acs.macromol.6b00302 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/15332 | |
| dc.identifier.volume | 49 | en_US |
| dc.identifier.wos | WOS:000375244600013 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Amer Chemical Soc | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Expanding the Realm of Soluble Narrow Band Gap Polymers With a Benzobisthiadiazole Derivative | en_US |
| dc.type | Article | en_US |