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A Camouflage Material: P- and N-Type Dopable Furan Based Low Band Gap Electrochromic Polymer and Its Edot Based Copolymer

dc.authorid Kivrak, Arif/0000-0003-4770-2686
dc.authorid Kavak, Emrah/0000-0002-6161-2030
dc.authorid Yavuz, Ejmer/0000-0002-1520-7915
dc.authorscopusid 56891345500
dc.authorscopusid 56891740900
dc.authorscopusid 56890823400
dc.authorscopusid 8694518300
dc.authorscopusid 54782763000
dc.authorwosid Kivrak, Arif/Aaq-8432-2021
dc.authorwosid Özkut, Merve/Aad-7011-2019
dc.authorwosid Kivrak, Arif/W-2196-2017
dc.authorwosid Kavak, Emrah/Gls-1399-2022
dc.contributor.author Kavak, Emrah
dc.contributor.author Us, Cansu N.
dc.contributor.author Yavuz, Ejmer
dc.contributor.author Kivrak, Arif
dc.contributor.author Ozkut, Merve Icli
dc.date.accessioned 2025-05-10T17:39:58Z
dc.date.available 2025-05-10T17:39:58Z
dc.date.issued 2015
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Kavak, Emrah; Kivrak, Arif] Yuzuncu Yil Univ, Dept Chem, Fac Sci, TR-65080 Van, Turkey; [Us, Cansu N.; Yavuz, Ejmer; Ozkut, Merve Icli] Yuzuncu Yil Univ, Dept Chem Engn, Fac Engn & Architecture, TR-65080 Van, Turkey en_US
dc.description Kivrak, Arif/0000-0003-4770-2686; Kavak, Emrah/0000-0002-6161-2030; Yavuz, Ejmer/0000-0002-1520-7915 en_US
dc.description.abstract A Donor-Acceptor-Donor (D-A-D) type monomer, 4,9-di(furan-2-yl)-6,7-diphenyl-[1,2,5]thiadiazolo[3,4g] quinoxaline (1), was synthesized via Stille Coupling reaction and polymerized electrochemically. The obtained polymer (P1) has low band gap (0.85 eV) and showed electrochromic property (pale mustard-colored in neutral state, grey in oxidized state and brown in reduced state). Moreover, copolymerization of 1 was carried out with EDOT for the formation of P(1-co-EDOT) which exhibits higher electrochemical stability than its homopolymer (P1) and have intriguing electrochromic property with a color change from the tunes of brown to the tunes of green. The band gap of copolymer was calculated as 1.1 eV. (C) 2015 Elsevier Ltd. All rights reserved. en_US
dc.description.sponsorship Scientific and Technological Research Council of Turkey [TUBITAK-113Z872]; Yuzuncu Yil University [2015-MIM-B112, 2013-FEN-B066] en_US
dc.description.sponsorship We want to express our thanks to the Scientific and Technological Research Council of Turkey (TUBITAK-113Z872) and Yuzuncu Yil University (2015-MIM-B112, 2013-FEN-B066) for their financial supports. en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.doi 10.1016/j.electacta.2015.09.148
dc.identifier.endpage 543 en_US
dc.identifier.issn 0013-4686
dc.identifier.issn 1873-3859
dc.identifier.scopus 2-s2.0-84943328657
dc.identifier.scopusquality Q1
dc.identifier.startpage 537 en_US
dc.identifier.uri https://doi.org/10.1016/j.electacta.2015.09.148
dc.identifier.uri https://hdl.handle.net/20.500.14720/15058
dc.identifier.volume 182 en_US
dc.identifier.wos WOS:000365075800066
dc.identifier.wosquality Q2
dc.language.iso en en_US
dc.publisher Pergamon-elsevier Science Ltd en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Electrochromism en_US
dc.subject Low Band Gap Polymer en_US
dc.subject Furan en_US
dc.subject Thiadiazolo[3,4-G]Quinoxaline en_US
dc.subject Donor-Acceptor-Donor (D-A-D) Approach en_US
dc.title A Camouflage Material: P- and N-Type Dopable Furan Based Low Band Gap Electrochromic Polymer and Its Edot Based Copolymer en_US
dc.type Article en_US

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