A Camouflage Material: P- and N-Type Dopable Furan Based Low Band Gap Electrochromic Polymer and Its Edot Based Copolymer
dc.authorid | Kivrak, Arif/0000-0003-4770-2686 | |
dc.authorid | Kavak, Emrah/0000-0002-6161-2030 | |
dc.authorid | Yavuz, Ejmer/0000-0002-1520-7915 | |
dc.authorscopusid | 56891345500 | |
dc.authorscopusid | 56891740900 | |
dc.authorscopusid | 56890823400 | |
dc.authorscopusid | 8694518300 | |
dc.authorscopusid | 54782763000 | |
dc.authorwosid | Kivrak, Arif/Aaq-8432-2021 | |
dc.authorwosid | Özkut, Merve/Aad-7011-2019 | |
dc.authorwosid | Kivrak, Arif/W-2196-2017 | |
dc.authorwosid | Kavak, Emrah/Gls-1399-2022 | |
dc.contributor.author | Kavak, Emrah | |
dc.contributor.author | Us, Cansu N. | |
dc.contributor.author | Yavuz, Ejmer | |
dc.contributor.author | Kivrak, Arif | |
dc.contributor.author | Ozkut, Merve Icli | |
dc.date.accessioned | 2025-05-10T17:39:58Z | |
dc.date.available | 2025-05-10T17:39:58Z | |
dc.date.issued | 2015 | |
dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
dc.department-temp | [Kavak, Emrah; Kivrak, Arif] Yuzuncu Yil Univ, Dept Chem, Fac Sci, TR-65080 Van, Turkey; [Us, Cansu N.; Yavuz, Ejmer; Ozkut, Merve Icli] Yuzuncu Yil Univ, Dept Chem Engn, Fac Engn & Architecture, TR-65080 Van, Turkey | en_US |
dc.description | Kivrak, Arif/0000-0003-4770-2686; Kavak, Emrah/0000-0002-6161-2030; Yavuz, Ejmer/0000-0002-1520-7915 | en_US |
dc.description.abstract | A Donor-Acceptor-Donor (D-A-D) type monomer, 4,9-di(furan-2-yl)-6,7-diphenyl-[1,2,5]thiadiazolo[3,4g] quinoxaline (1), was synthesized via Stille Coupling reaction and polymerized electrochemically. The obtained polymer (P1) has low band gap (0.85 eV) and showed electrochromic property (pale mustard-colored in neutral state, grey in oxidized state and brown in reduced state). Moreover, copolymerization of 1 was carried out with EDOT for the formation of P(1-co-EDOT) which exhibits higher electrochemical stability than its homopolymer (P1) and have intriguing electrochromic property with a color change from the tunes of brown to the tunes of green. The band gap of copolymer was calculated as 1.1 eV. (C) 2015 Elsevier Ltd. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey [TUBITAK-113Z872]; Yuzuncu Yil University [2015-MIM-B112, 2013-FEN-B066] | en_US |
dc.description.sponsorship | We want to express our thanks to the Scientific and Technological Research Council of Turkey (TUBITAK-113Z872) and Yuzuncu Yil University (2015-MIM-B112, 2013-FEN-B066) for their financial supports. | en_US |
dc.description.woscitationindex | Science Citation Index Expanded | |
dc.identifier.doi | 10.1016/j.electacta.2015.09.148 | |
dc.identifier.endpage | 543 | en_US |
dc.identifier.issn | 0013-4686 | |
dc.identifier.issn | 1873-3859 | |
dc.identifier.scopus | 2-s2.0-84943328657 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 537 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.electacta.2015.09.148 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14720/15058 | |
dc.identifier.volume | 182 | en_US |
dc.identifier.wos | WOS:000365075800066 | |
dc.identifier.wosquality | Q2 | |
dc.language.iso | en | en_US |
dc.publisher | Pergamon-elsevier Science Ltd | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Electrochromism | en_US |
dc.subject | Low Band Gap Polymer | en_US |
dc.subject | Furan | en_US |
dc.subject | Thiadiazolo[3,4-G]Quinoxaline | en_US |
dc.subject | Donor-Acceptor-Donor (D-A-D) Approach | en_US |
dc.title | A Camouflage Material: P- and N-Type Dopable Furan Based Low Band Gap Electrochromic Polymer and Its Edot Based Copolymer | en_US |
dc.type | Article | en_US |