Design of Novel Binuclear Phthalocyanines Formed by Dioxyphenyl Bridges: Synthesis and Investigation of Thermal and Antioxidant Properties
| dc.authorid | Dundar, Abdurrahman/0000-0002-7930-1054 | |
| dc.authorid | Okumus, Veysi/0000-0002-5505-2700 | |
| dc.authorscopusid | 55663235100 | |
| dc.authorscopusid | 55366812100 | |
| dc.authorscopusid | 36024441800 | |
| dc.authorscopusid | 25623213000 | |
| dc.authorwosid | Okumuş, Veysi/Aai-6772-2021 | |
| dc.authorwosid | Gümüş, Ilkay/Y-9132-2018 | |
| dc.authorwosid | Dundar, Abdurrahman/Aan-2569-2020 | |
| dc.contributor.author | Agirtas, M. Salih | |
| dc.contributor.author | Gumus, Ilkay | |
| dc.contributor.author | Okumus, Veysi | |
| dc.contributor.author | Dundar, Abdurrahman | |
| dc.date.accessioned | 2025-05-10T16:48:39Z | |
| dc.date.available | 2025-05-10T16:48:39Z | |
| dc.date.issued | 2012 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Agirtas, M. Salih; Gumus, Ilkay] Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey; [Okumus, Veysi; Dundar, Abdurrahman] Siirt Univ, Fac Arts & Sci, Dept Biol, TR-56100 Siirt, Turkey | en_US |
| dc.description | Dundar, Abdurrahman/0000-0002-7930-1054; Okumus, Veysi/0000-0002-5505-2700 | en_US |
| dc.description.abstract | 4, 4'-(1, 4-Phenylenebis(oxy)diphthalonitrile was synthesized by reaction of hydroquinone with 4-nitrophthalonitrile. Binuclear metallophthalocyanines 24 were obtained by the reaction between 4, 4'-(1, 4-phenylenebis(oxy)diphthalonitrile and 4-(benzo [d] 1,3 dioxol-5-ylmethoxy)phthalonitrile in the presence of metal salts. These new compounds were characterized by using elemental analysis, FTIR, 1H-NMR and UV/Vis spectroscopic data. Thermal properties of phthalocyanines 2-4 were investigated by TG and DTA. In addition, antioxidant properties of compounds II, 3 and 4 were investigated. Their radical-scavenging capacity and chelating effects was fully studied. The maximum 1, 1-diphenyl-2-picrylhydrazyl radicals (DPPH) were obtained from compound 3. Chelating effects on ferrous ions were 91.6?% at concentration of 100 mg?L1 with compound II. | en_US |
| dc.description.sponsorship | Research Fund of Yuzuncu Yil University [2010-FBE-YL151] | en_US |
| dc.description.sponsorship | This study was supported by the Research Fund of Yuzuncu Yil University (2010-FBE-YL151). | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1002/zaac.201200220 | |
| dc.identifier.endpage | 1872 | en_US |
| dc.identifier.issn | 0044-2313 | |
| dc.identifier.issue | 11 | en_US |
| dc.identifier.scopus | 2-s2.0-84866723620 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 1868 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/zaac.201200220 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/1606 | |
| dc.identifier.volume | 638 | en_US |
| dc.identifier.wos | WOS:000308991600034 | |
| dc.identifier.wosquality | Q4 | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley-v C H verlag Gmbh | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Phthalocyanines | en_US |
| dc.subject | Antioxidants | en_US |
| dc.subject | Thermal Properties | en_US |
| dc.subject | Synthesis | en_US |
| dc.subject | Binuclear Complexes | en_US |
| dc.title | Design of Novel Binuclear Phthalocyanines Formed by Dioxyphenyl Bridges: Synthesis and Investigation of Thermal and Antioxidant Properties | en_US |
| dc.type | Article | en_US |