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Palladium(0) Nanoparticles Supported on Metal Organic Framework as Highly Active and Reusable Nanocatalyst in Dehydrogenation of Dimethylamine-Borane

dc.authorid Ozkar, Saim/0000-0002-6302-1429
dc.authorid Gulcan, Mehmet/0000-0002-3921-8811
dc.authorscopusid 8226754300
dc.authorscopusid 14521641300
dc.authorscopusid 7003408746
dc.authorwosid Ozkar, S/Aba-1983-2020
dc.authorwosid Gülcan, Mehmet/Aat-1504-2021
dc.authorwosid Zahmakiran, Mehmet/F-7120-2014
dc.contributor.author Gulcan, Mehmet
dc.contributor.author Zahmakiran, Mehmet
dc.contributor.author Ozkar, Saim
dc.date.accessioned 2025-05-10T17:45:43Z
dc.date.available 2025-05-10T17:45:43Z
dc.date.issued 2014
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Gulcan, Mehmet; Zahmakiran, Mehmet] Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey; [Ozkar, Saim] Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey en_US
dc.description Ozkar, Saim/0000-0002-6302-1429; Gulcan, Mehmet/0000-0002-3921-8811 en_US
dc.description.abstract Palladium(0) nanoparticles supported on the external surface of Cu-3(btc)(2) framework (PdNPs@Cu-3(btc)(2)) were in-situ generated from the reduction of Pd(acac)2 precursor impregnated on the Cu-3(btc)(2) support during the dehydrogenation of dimethylamine-borane in toluene at room temperature. The characterization of PdNPs@Cu-3(btc)(2) by using advanced analytical techniques shows the formation of well-dispersed palladium(0) nanoparticles supported on Cu-3(btc)(2) surface. These new palladium(0) nanoparticles were found to be the most active and the longest-lived nanocatalyst with superior reusability performance in the dehydrogenation of dimethylamine-borane at room temperature. (C) 2013 Elsevier B.V. All rights reserved. en_US
dc.description.sponsorship Turkish Academy of Sciences en_US
dc.description.sponsorship Partial support by Turkish Academy of Sciences is gratefully acknowledged. en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.doi 10.1016/j.apcatb.2013.09.007
dc.identifier.endpage 401 en_US
dc.identifier.issn 0926-3373
dc.identifier.issn 1873-3883
dc.identifier.scopus 2-s2.0-84885401698
dc.identifier.scopusquality Q1
dc.identifier.startpage 394 en_US
dc.identifier.uri https://doi.org/10.1016/j.apcatb.2013.09.007
dc.identifier.uri https://hdl.handle.net/20.500.14720/16424
dc.identifier.volume 147 en_US
dc.identifier.wos WOS:000330489400044
dc.identifier.wosquality N/A
dc.language.iso en en_US
dc.publisher Elsevier Science Bv en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Nanocatalyst en_US
dc.subject Palladium Nanoparticles en_US
dc.subject Metal-Organic Framework en_US
dc.subject Dimethylamine-Borane en_US
dc.subject Hydrogen en_US
dc.title Palladium(0) Nanoparticles Supported on Metal Organic Framework as Highly Active and Reusable Nanocatalyst in Dehydrogenation of Dimethylamine-Borane en_US
dc.type Article en_US

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