Eco-Friendly Synthesis of Carboxymethyl Cellulose-Stabilized Ru0.57co0.43 Nanoclusters as Extremely Efficient and Durable Catalysts for Hydrolytic Dehydrogenation of Methylamine Borane
| dc.authorscopusid | 56850258700 | |
| dc.authorscopusid | 15132683900 | |
| dc.authorwosid | Rakap, Murat/Jpa-3399-2023 | |
| dc.contributor.author | Abay, Bayram | |
| dc.contributor.author | Rakap, Murat | |
| dc.date.accessioned | 2025-05-10T17:07:51Z | |
| dc.date.available | 2025-05-10T17:07:51Z | |
| dc.date.issued | 2020 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Abay, Bayram] Van Yuzuncu Yil Univ, Dept Chem, TR-65080 Van, Turkey; [Rakap, Murat] Van Yuzuncu Yil Univ, Maritime Fac, TR-65080 Van, Turkey | en_US |
| dc.description.abstract | Herein, we report the first ever eco-friendly and easy synthesis of carboxymethyl cellulose-stabilized RuCo nanoclusters (Ru0.57Co0.43@CMC) and their use as highly efficient and durable catalysts to produce hydrogen from hydrolytic dehydrogenation of methylamine borane (MeAB). Ru0.57Co0.43@CMC nanoclusters are easily synthesized from synchronous chemical reduction of suitable water-soluble cobalt and ruthenium salts by sodium borohydride. They are identified by some advanced methods including ultraviolet-visible spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. All related kinetic studies show that Ru0.57Co0.43@CMC nanoclusters are extremely efficient, relatively cost-saver, and durable catalysts in hydrolytic dehydrogenation of MeAB at very low temperatures. They provided the highest ever initial turnover frequency value of 327.1 min(-1) and also the apparent activation energy of 49.7 kJ/mol for the hydrolytic dehydrogenation of MeAB. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1021/acssuschemeng.0c05051 | |
| dc.identifier.endpage | 16204 | en_US |
| dc.identifier.issn | 2168-0485 | |
| dc.identifier.issue | 43 | en_US |
| dc.identifier.scopus | 2-s2.0-85096084502 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 16197 | en_US |
| dc.identifier.uri | https://doi.org/10.1021/acssuschemeng.0c05051 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/6902 | |
| dc.identifier.volume | 8 | en_US |
| dc.identifier.wos | WOS:000588740300015 | |
| dc.identifier.wosquality | Q1 | |
| dc.language.iso | en | en_US |
| dc.publisher | Amer Chemical Soc | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Ruthenium | en_US |
| dc.subject | Cobalt | en_US |
| dc.subject | Nanoparticle | en_US |
| dc.subject | Hydrolysis Of Methylamine Borane | en_US |
| dc.subject | Cmc | en_US |
| dc.title | Eco-Friendly Synthesis of Carboxymethyl Cellulose-Stabilized Ru0.57co0.43 Nanoclusters as Extremely Efficient and Durable Catalysts for Hydrolytic Dehydrogenation of Methylamine Borane | en_US |
| dc.type | Article | en_US |