Catalytic Pyrolysis of Tetraselmis and Isochrysis Microalgae by Nickel Ceria Based Catalysts for Hydrocarbon Production

Abstract

The catalytic pyrolysis of Tetraselmis sp. and Isochrysis sp. was carried out over ceria based catalysts in a fixed bed reactor. There was a clear effect of the catalysts on the product yields and quality, with the catalysts able to recover a large fraction of the starting microalgae energy (67-77%) in the bio-oils. Biooil yield was found to be higher in presence of Ni-Ce/Al2O3 and Ni-C/ZrO2 (26 wt.%). The produced bio-oils had HHVs (higher heating values) of 34-35 MJ/kg and suffered strong deoxygenation, with O level decreased from 40-41% in the starting microalgae to 9-15%. Also, 15-20% N removal was obtained using the ceria based catalysts. The oxygen contents in the bio-oils were remarkably lower than those previously obtained using ZSM-5 (25%) and other species without catalyst (17-24%). H-1 NMR and GC-MS analysis showed that the bio-oils were enriched in aliphatics and depleted in N-compounds and water using the ceria based catalysts. (C) 2016 Elsevier Ltd. All rights reserved.