Analysis of Physical and Thermodynamic Properties of Poly(2-Phenyl Polymer With Inverse Gas Chromatography
| dc.contributor.author | Karagöz, MH | |
| dc.contributor.author | Zorer, ÖS | |
| dc.contributor.author | Ilter, Z | |
| dc.date.accessioned | 2025-05-10T17:29:38Z | |
| dc.date.available | 2025-05-10T17:29:38Z | |
| dc.date.issued | 2006 | |
| dc.description | Selcuk Zorer, Ozlem/0000-0002-6486-8365 | en_US |
| dc.description.abstract | In this study, physical and thermodynamic properties of poly(2-phenyl-1,3-dioxolane-4-yl-methyl-methacrylate-co-styrene) (PDMMA-ST) were investigated by using inverse gas chromatography. Two groups of solvents with different chemical natures and polarities were used to obtain information about PDMMA-ST-solvent interactions: alcohols and alkanes. The specific retention volume (V-g(0)), the sorption enthalpy (Delta H-1(S)), sorption free energy (Delta G(1)(S)), sorption entropy (Delta S-1(S)), the weight fraction activity coefficients of solute probes at infinite dilution (Omega(infinity)(1)), and Flory-Huggins interaction parameters (chi(infinity)(12)) between polymer and solvents were determined for the interactions of PDMMA-ST with alcohols and alkanes by inverse gas chromatography in the temperature range of 333-473 K. Also, the solubility parameters of PDMMA-ST at infinite dilution were found by plotting the graph of [(delta(2)(1)/RT) - chi(infinity)(12)/V-1] versus solubility parameters, delta(1), of probes. | en_US |
| dc.identifier.doi | 10.1080/03602550600611859 | |
| dc.identifier.issn | 0360-2559 | |
| dc.identifier.scopus | 2-s2.0-33745316582 | |
| dc.identifier.uri | https://doi.org/10.1080/03602550600611859 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/12411 | |
| dc.language.iso | en | en_US |
| dc.publisher | Taylor & Francis inc | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Polymer | en_US |
| dc.subject | Thermodynamic Properties | en_US |
| dc.subject | Inverse Gas Chromatography | en_US |
| dc.title | Analysis of Physical and Thermodynamic Properties of Poly(2-Phenyl Polymer With Inverse Gas Chromatography | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.id | Selcuk Zorer, Ozlem/0000-0002-6486-8365 | |
| gdc.author.scopusid | 14021679000 | |
| gdc.author.scopusid | 23135835100 | |
| gdc.author.scopusid | 6603099288 | |
| gdc.author.wosid | İlter, Zülfi̇ye/W-6790-2018 | |
| gdc.coar.access | metadata only access | |
| gdc.coar.type | text::journal::journal article | |
| gdc.description.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| gdc.description.departmenttemp | Yuzuncu Yil Univ, Fac Sci & Arts, Dept Chem, Van, Turkey; Firat Univ, Fac Sci & Arts, Dept Chem, Elazig, Turkey | en_US |
| gdc.description.endpage | 789 | en_US |
| gdc.description.issue | 7 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | N/A | |
| gdc.description.startpage | 785 | en_US |
| gdc.description.volume | 45 | en_US |
| gdc.description.woscitationindex | Science Citation Index Expanded | |
| gdc.description.wosquality | N/A | |
| gdc.identifier.wos | WOS:000238420100003 | |
| gdc.index.type | WoS | |
| gdc.index.type | Scopus |