In Situ Formed Ruthenium(0) Nanoparticles Supported on Tio2 Catalyzed Hydrogen Generation From Aqueous Ammonia-Borane Solution at Room Temperature Under Air
| dc.authorid | Karatas, Yasar/0000-0002-9171-7781 | |
| dc.authorid | Gulcan, Mehmet/0000-0002-3921-8811 | |
| dc.authorscopusid | 56971352200 | |
| dc.authorscopusid | 57081059100 | |
| dc.authorscopusid | 8226754300 | |
| dc.authorwosid | Gülcan, Mehmet/Aat-1504-2021 | |
| dc.authorwosid | Karatas, Yasar/Aam-7945-2020 | |
| dc.contributor.author | Konus, Nihayet | |
| dc.contributor.author | Karatas, Yasar | |
| dc.contributor.author | Gulcan, Mehmet | |
| dc.date.accessioned | 2025-05-10T17:40:54Z | |
| dc.date.available | 2025-05-10T17:40:54Z | |
| dc.date.issued | 2016 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Konus, Nihayet; Karatas, Yasar; Gulcan, Mehmet] Yuzuncu Yil Univ, Dept Chem, Fac Sci, TR-65080 Van, Turkey | en_US |
| dc.description | Karatas, Yasar/0000-0002-9171-7781; Gulcan, Mehmet/0000-0002-3921-8811 | en_US |
| dc.description.abstract | Herein, the authors report that TiO2 supported ruthenium nanoparticles (Ru(0)/TiO2) during hydrolysis starting with RuCl3/TiO2 precatalyst act as highly active, long-lived, and reusable nanocatalyst in the hydrogen generation from the hydrolysis of ammonia-borane (NH3BH3) at room temperature. The resulting Ru(0)/TiO2 catalyze hydrogen generation from the hydrolysis of ammonia-borane with an initial turnover frequency value of 200min(-1) at 25 +/- 0.1 degrees C. More importantly, Ru(0)/TiO2 are stable enough to be isolated and bottled as solid material, which can be reused as active catalyst under the identical conditions of the first run. | en_US |
| dc.description.sponsorship | Presidency of Scientific Research Projects of University of Yuzuncu Yil | en_US |
| dc.description.sponsorship | The authors thank the Presidency of Scientific Research Projects of University of Yuzuncu Yil for the financial support. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1080/15533174.2014.988808 | |
| dc.identifier.endpage | 542 | en_US |
| dc.identifier.issn | 1553-3174 | |
| dc.identifier.issn | 1553-3182 | |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopus | 2-s2.0-84947724949 | |
| dc.identifier.scopusquality | N/A | |
| dc.identifier.startpage | 534 | en_US |
| dc.identifier.uri | https://doi.org/10.1080/15533174.2014.988808 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/15340 | |
| dc.identifier.volume | 46 | en_US |
| dc.identifier.wos | WOS:000364854600002 | |
| dc.identifier.wosquality | N/A | |
| dc.language.iso | en | en_US |
| dc.publisher | Taylor & Francis inc | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Ruthenium | en_US |
| dc.subject | Nanoparticles | en_US |
| dc.subject | Titanium(Iv) Oxide | en_US |
| dc.subject | Ammonia-Borane | en_US |
| dc.subject | Hydrogen | en_US |
| dc.title | In Situ Formed Ruthenium(0) Nanoparticles Supported on Tio2 Catalyzed Hydrogen Generation From Aqueous Ammonia-Borane Solution at Room Temperature Under Air | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |