Synthesis of 2-Methyl Through Reaction of Acetylketene With Terminal Acetylenes in Presence of Gold (I)
| dc.authorid | Aslanoglu, Furgan/0000-0002-5740-1716 | |
| dc.authorscopusid | 12241099400 | |
| dc.authorwosid | Aslanoglu, Furgan/D-8014-2019 | |
| dc.contributor.author | Aslanoglu, Furgan | |
| dc.date.accessioned | 2025-05-10T17:12:04Z | |
| dc.date.available | 2025-05-10T17:12:04Z | |
| dc.date.issued | 2022 | |
| dc.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| dc.department-temp | [Aslanoglu, Furgan] Van Yuzuncu Yil Univ, Dept Chem, TR-65080 Van, Turkey | en_US |
| dc.description | Aslanoglu, Furgan/0000-0002-5740-1716 | en_US |
| dc.description.abstract | In this study, 2,6-trimethyl-4H-1,3-dioxin-4-one compound, which is a source of Acetylketene, was reacted with terminal alkynes in presence of IPrAuCl (1,3-Bis(2,6-diisopropylphenyl-imidazol-2-ylidene)gold(I) chloride) catalyst and a new synthesis method for 2-methyl-pyran-4-one compounds has been developed. It was observed that the yields were very low when this reaction was carried out without using a catalyst. However, 95 % yield was obtained when this reaction was performed in the presence of a IPrAuCl catalyst. | en_US |
| dc.description.sponsorship | Van Yuzuncu Yil University [FBA-2019-8435] | en_US |
| dc.description.sponsorship | The authors thank Van Yuzuncu Yil University for financial support (Grant number: FBA-2019-8435). | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.1002/slct.202201089 | |
| dc.identifier.issn | 2365-6549 | |
| dc.identifier.issue | 26 | en_US |
| dc.identifier.scopus | 2-s2.0-85134052758 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.uri | https://doi.org/10.1002/slct.202201089 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/7794 | |
| dc.identifier.volume | 7 | en_US |
| dc.identifier.wos | WOS:000824678600005 | |
| dc.identifier.wosquality | Q3 | |
| dc.institutionauthor | Aslanoglu, Furgan | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley-v C H verlag Gmbh | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Acetylketene | en_US |
| dc.subject | Gold(I) | en_US |
| dc.subject | 2-Methyl-Pyran-4-One | en_US |
| dc.subject | Terminal Acetylenes | en_US |
| dc.subject | 2 | en_US |
| dc.subject | 2 | en_US |
| dc.subject | 6-Trimethyl-4H-1 | en_US |
| dc.subject | 3-Dioxin-4-One | en_US |
| dc.title | Synthesis of 2-Methyl Through Reaction of Acetylketene With Terminal Acetylenes in Presence of Gold (I) | en_US |
| dc.type | Article | en_US |