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Palladium(Ii) and Platinum(Ii) Complexes of a Symmetric Schiff Base Derived From 2,6,diformyl-4 With N-Aminopyrimidine: Synthesis, Characterization and Detection of Dna Interaction by Voltammetry

dc.authorid Celebi, Metin/0000-0003-1475-8878
dc.authorid Senturk, Zuhre/0000-0002-0356-9345
dc.authorid Yardim, Yavuz/0000-0002-9587-096X
dc.authorscopusid 35732479200
dc.authorscopusid 25951378700
dc.authorscopusid 55511747958
dc.authorscopusid 7004177719
dc.authorwosid Sönmez, Mehmet/V-5046-2018
dc.authorwosid Senturk, Zuhre/Aas-5179-2020
dc.authorwosid Celebi, Metin/Gwd-1423-2022
dc.contributor.author Sonmez, Mehmet
dc.contributor.author Celebi, Metin
dc.contributor.author Yardim, Yavuz
dc.contributor.author Senturk, Zuhre
dc.date.accessioned 2025-05-10T16:48:54Z
dc.date.available 2025-05-10T16:48:54Z
dc.date.issued 2010
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Sonmez, Mehmet] Gaziantep Univ, Fac Sci & Letters, Dept Chem, TR-27310 Gaziantep, Turkey; [Celebi, Metin] Yuzuncu Yil Univ, Dept Inorgan Chem, Fac Sci & Letters, TR-65080 Van, Turkey; [Yardim, Yavuz; Senturk, Zuhre] Yuzuncu Yil Univ, Dept Analyt Chem, Fac Sci & Letters, TR-65080 Van, Turkey en_US
dc.description Celebi, Metin/0000-0003-1475-8878; Senturk, Zuhre/0000-0002-0356-9345; Yardim, Yavuz/0000-0002-9587-096X en_US
dc.description.abstract The two new mononuclear complexes were prepared by reacting symmetric Schiff base, containing pyrimidine rings and the metal chlorides of Pd(II) and Pt(II) in methanol. The mononuclear structure of the complexes was confirmed on the basis of elemental analyses, magnetic susceptibility, IR, UV-Vis, NMR, DTA/TGA and API-ES mass spectral data. The interaction of these metal complexes with fish sperm double-stranded DNA (dsDNA) was studied electrochemically based on the oxidation signals of guanine and adenine. Differential pulse (DP) voltammetry by using renewable pencil graphite electrode was employed to monitor the DNA interaction at the surface or in solution. The results indicate that Pd(II) and (Pt) complexes with Schiff base ligand having pyrimidine rings strongly interacted with DNA. (C) 2010 Elsevier Masson SAS. All rights reserved. en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.doi 10.1016/j.ejmech.2010.06.016
dc.identifier.endpage 4220 en_US
dc.identifier.issn 0223-5234
dc.identifier.issn 1768-3254
dc.identifier.issue 9 en_US
dc.identifier.pmid 20619510
dc.identifier.scopus 2-s2.0-77955555022
dc.identifier.scopusquality Q1
dc.identifier.startpage 4215 en_US
dc.identifier.uri https://doi.org/10.1016/j.ejmech.2010.06.016
dc.identifier.uri https://hdl.handle.net/20.500.14720/1682
dc.identifier.volume 45 en_US
dc.identifier.wos WOS:000281568600085
dc.identifier.wosquality Q1
dc.language.iso en en_US
dc.publisher Elsevier France-editions Scientifiques Medicales Elsevier en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Pd(Ii) And Pt(Ii) Complexes Of N-Aminopyrimidine Schiff Base en_US
dc.subject Synthesis en_US
dc.subject Characterization en_US
dc.subject Dna Interaction en_US
dc.subject Voltammetry en_US
dc.subject Guanine And Adenine Oxidation en_US
dc.title Palladium(Ii) and Platinum(Ii) Complexes of a Symmetric Schiff Base Derived From 2,6,diformyl-4 With N-Aminopyrimidine: Synthesis, Characterization and Detection of Dna Interaction by Voltammetry en_US
dc.type Article en_US

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