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Synthesis of Pyrrole-Fused C,n-Cyclic Azomethine Imines and Pyrazolopyrrolopyrazines: Analysis of Their Aromaticity Using Nucleus-Independent Chemical Shifts Values

dc.authorid Menges, Nurettin/0000-0002-5990-6275
dc.authorscopusid 36872923100
dc.authorscopusid 23973608700
dc.authorscopusid 57226866516
dc.authorscopusid 55550270900
dc.authorscopusid 7006382595
dc.authorwosid Keskin, Selbi/Jan-3999-2023
dc.authorwosid Menges, Nurettin/F-9678-2016
dc.contributor.author Ozer, Merve Sinem
dc.contributor.author Menges, Nurettin
dc.contributor.author Keskin, Selbi
dc.contributor.author Sahin, Ertan
dc.contributor.author Balci, Metin
dc.date.accessioned 2025-05-10T17:39:35Z
dc.date.available 2025-05-10T17:39:35Z
dc.date.issued 2016
dc.department T.C. Van Yüzüncü Yıl Üniversitesi en_US
dc.department-temp [Ozer, Merve Sinem; Menges, Nurettin; Keskin, Selbi; Balci, Metin] Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey; [Menges, Nurettin] Yuzuncu Yil Univ, Fac Pharm, TR-65100 Van, Turkey; [Sahin, Ertan] Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey; [Keskin, Selbi] Giresun Univ, Dept Chem, TR-28100 Giresun, Turkey en_US
dc.description Menges, Nurettin/0000-0002-5990-6275 en_US
dc.description.abstract The AgOTf-catalyzed reaction of C-2 substituted pyrrole hydrazones having an N-propargyl group was studied. The selective 6-endo-dig mode of cyclization was observed, giving rise to the formation of pyrrole-fused C,N-cyclic azomethine imine derivatives. The reaction of one azomethine imine derivative with various dipolarophiles resulted in the formation of cycloadducts having a pyrazolopyrrolopyrazine skeleton. The aromaticity of C,N-cyclic azomethine imines as well as that of pyrazolopyrrolopyrazines was determined by calculating of nucleus-independent chemical shifts values. en_US
dc.description.sponsorship Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-112 T360]; Yuzuncu Yil University [2014-ECZ-B170]; Turkish Academy of Sciences (TUBA); Middle East Technical University (METU) en_US
dc.description.sponsorship Financial support from the Scientific and Technological Research Council of Turkey (TUBITAK, Grant No. TBAG-112 T360), Yuzuncu Yil University (Grant No. 2014-ECZ-B170), the Turkish Academy of Sciences (TUBA), and the Middle East Technical University (METU) is gratefully acknowledged. en_US
dc.description.woscitationindex Science Citation Index Expanded - Index Chemicus
dc.identifier.doi 10.1021/acs.orglett.5b03434
dc.identifier.endpage 411 en_US
dc.identifier.issn 1523-7060
dc.identifier.issn 1523-7052
dc.identifier.issue 3 en_US
dc.identifier.pmid 26752224
dc.identifier.scopus 2-s2.0-84957824168
dc.identifier.scopusquality Q1
dc.identifier.startpage 408 en_US
dc.identifier.uri https://doi.org/10.1021/acs.orglett.5b03434
dc.identifier.uri https://hdl.handle.net/20.500.14720/14926
dc.identifier.volume 18 en_US
dc.identifier.wos WOS:000369771800017
dc.identifier.wosquality Q1
dc.language.iso en en_US
dc.publisher Amer Chemical Soc en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.title Synthesis of Pyrrole-Fused C,n-Cyclic Azomethine Imines and Pyrazolopyrrolopyrazines: Analysis of Their Aromaticity Using Nucleus-Independent Chemical Shifts Values en_US
dc.type Article en_US

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