Gold-Catalyzed Oxime-Oxime Rearrangement
| dc.contributor.author | Guven, Sinem | |
| dc.contributor.author | Ozer, Merve Sinem | |
| dc.contributor.author | Kaya, Serdal | |
| dc.contributor.author | Menges, Nurettin | |
| dc.contributor.author | Balci, Metin | |
| dc.date.accessioned | 2025-05-10T17:37:39Z | |
| dc.date.available | 2025-05-10T17:37:39Z | |
| dc.date.issued | 2015 | |
| dc.description | Menges, Nurettin/0000-0002-5990-6275 | en_US |
| dc.description.abstract | The gold-catalyzed reaction of pyrrole and indole oximes having a propargyl group attached to the nitrogen atom was studied. The selective 6-endo-dig mode of cyclization was observed for the terminal alkynes giving rise to the formation of pyrazine N-oxides in the presence of a gold catalyst. However, the reaction with substituted alkyne transferred the oxime functionality intramolecularly from one carbon atom to another via the 7-endo-dig cyclization process. This transformation is unprecedented in the literature and is named an oximeoxime rearrangement. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-112 T360]; Turkish Academy of Sciences (TUBA); Middle East Technical University (METU) | en_US |
| dc.description.sponsorship | Financial support from the Scientific and Technological Research Council of Turkey (TUBITAK, Grant No. TBAG-112 T360), the Turkish Academy of Sciences (TUBA), and Middle East Technical University (METU) is gratefully acknowledged. We also thank Research Assistant Ozlem Sari (METU) for her help with calculations. | en_US |
| dc.identifier.doi | 10.1021/acs.orglett.5b01041 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.issn | 1523-7052 | |
| dc.identifier.scopus | 2-s2.0-84930633059 | |
| dc.identifier.uri | https://doi.org/10.1021/acs.orglett.5b01041 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14720/14438 | |
| dc.language.iso | en | en_US |
| dc.publisher | Amer Chemical Soc | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Gold-Catalyzed Oxime-Oxime Rearrangement | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.id | Menges, Nurettin/0000-0002-5990-6275 | |
| gdc.author.scopusid | 57204732269 | |
| gdc.author.scopusid | 36872923100 | |
| gdc.author.scopusid | 56673662600 | |
| gdc.author.scopusid | 23973608700 | |
| gdc.author.scopusid | 7006382595 | |
| gdc.author.wosid | Kaya, Serdal/P-3609-2018 | |
| gdc.author.wosid | Guven, Sinem/P-3273-2019 | |
| gdc.author.wosid | Menges, Nurettin/F-9678-2016 | |
| gdc.coar.access | metadata only access | |
| gdc.coar.type | text::journal::journal article | |
| gdc.description.department | T.C. Van Yüzüncü Yıl Üniversitesi | en_US |
| gdc.description.departmenttemp | [Guven, Sinem; Ozer, Merve Sinem; Kaya, Serdal; Menges, Nurettin; Balci, Metin] Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey; [Kaya, Serdal] Giresun Univ, Dept Chem, TR-28200 Giresun, Turkey; [Menges, Nurettin] Yuzuncu Yil Univ, Fac Pharm, TR-65100 Van, Turkey | en_US |
| gdc.description.endpage | 2663 | en_US |
| gdc.description.issue | 11 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q1 | |
| gdc.description.startpage | 2660 | en_US |
| gdc.description.volume | 17 | en_US |
| gdc.description.woscitationindex | Science Citation Index Expanded - Index Chemicus - Current Chemical Reactions | |
| gdc.description.wosquality | Q1 | |
| gdc.identifier.pmid | 25992473 | |
| gdc.identifier.wos | WOS:000355962200025 | |
| gdc.index.type | WoS | |
| gdc.index.type | Scopus | |
| gdc.index.type | PubMed |